期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 19, 页码 9402-9408出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01611
关键词
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资金
- NSFC [21502183]
- Fundamental Research Funds for the Central Universities [WK2060190041]
The first enantioselective heteroannulation of 1,3-dienes by 2-iodoanilines and 2-iodobenzylic alcohols is described. The application of a BINOL-derived phosphoramidite ligand bearing electron-withdrawing substituents is the key to obtaining high enantioselectivity. This protocol provides an efficient way to access optically active chiral indolines and isochromans from readily available starting materials.
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