期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 15, 页码 6223-6234出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00526
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资金
- Academia Sinica, Taiwan
2,3,9,10-Substituted pentacene tetraesters and pentacene diester-dinitriles were synthesized. These pentacene derivatives underwent an unusual solid state [4 + 4] thermal dimerization with good efficiency and complete stereo selectivity. This observation indicates this series of pentacene derivatives adopt pi-pi stacking geometry with large mutual overlap in solid state. This notion was confirmed by molecualr dynamic simulation.
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