期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 11, 页码 4682-4689出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00592
关键词
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资金
- Foundation Research Project of Jiangsu Province (The Natural Science Foundation) [BK20141359]
- 333 high level talent project of JiangSu Province
We reveal here a direct autoxidative phosphorylation of heteroarenes induced by oxygen under metal-free and solvent-free conditions. This new methodology provides an economical, operationally simple, and environmentally friendly approach toward (Het)C(sp(2))-P formation with medium to excellent yields. Heteroarenes including thiazole and quinoxaline derivatives are applicable under standard conditions, which is testified via a radical mechanism.
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