期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 4, 页码 1610-1616出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b02777
关键词
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资金
- PAPD (Priority Academic Program Development of Jiangsu Higher Education Institutions)
An efficient one-pot synthesis of alpha-iminonitriles from readily available aryl halides via palladium-catalyzed double isocyanide insertion and elimination has been developed, without using various hypertoxic cyanides and excess oxidants. Furthermore, the utility of this reaction was demonstrated by the rapid total synthesis of quinoxaline and the reaction of functional groups exchanged with aryl halides.
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