In this study, high temperature catalytic hydrogenolysis was performed on softwood lignins, resulting in high monomer yields of 62% and 43.5%. The cleavage of intermolecular bonds and the use of Pd/C catalyst were found to be crucial for achieving such high yields.
The catalytic hydrogenolysis of softwood lignins is normally conducted at temperatures below 200 degrees C but tends to provide monomer yields of less than 30 mol% as a consequence of the non-cleavable 4-O-5 and condensed (C-C) linkages of phenylpropane units in lignin. In the present study, catalytic hydrogenolysis at higher temperatures (250-350 degrees C) with the addition of Pd/C and H-2 in anisole provided very high monomer yields of 62 and 43.5 mol% (based on the quantity of aromatic rings in the original lignin) from milled wood lignin and organosolv lignin, respectively. Both these materials were isolated from Japanese cedar wood (a softwood). An analysis of the dimeric products and catalytic hydrogenolysis trials using model dimers established that the cleavage of 4-O-5 and condensed bonds was responsible for these high monomer yields. Specifically, C-alpha-aryl-type condensed bonds formed by condensation reactions during pyrolysis and the organosolv process were efficiently cleaved. This cleavage favored the production of monomers because condensation forming C-alpha-aryl bonds normally inhibit monomer formation to a significant extent. The undesirable saturation of aromatic rings was also suppressed at such high temperatures. The Pd/C catalyst but not the addition of H-2 was determined to be necessary for high monomer yields and the pyrolytic degradation of the lignin evidently played an important role in this transformation. On the basis of these data, the high temperature process reported herein is termed pyrolysis-assisted catalytic hydrogenolysis.
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