Adsorptive removal of thiophene by using water based silver nanofluid

In this work, a simple, eco-friendly, and energy-efficient protocol was used for the removal of thiophene as a model for the sulfur compounds present in gasoline. The water-based silver nanofluid was prepared via the chemical reduction method, using tannic acid as both a reducing and stabilizing agent. The prepared silver nanoparticles (AgNPs) were characterized using X-ray diffraction (XRD), dynamic light scattering (DLS), ultra-violet-visible spectroscopy, and transmission electron microscope (TEM). For studying the adsorption efficiency of the silver nanoparticles, several parameters were evaluated, such as the contact time, the size and stability of the nanoparticles, the concentrations of AgNPs, and the thiophene. The silver nanoparticle, of size 8.3 +/- 2 nm, showed the highest adsorption efficiency (i.e., 88.4 %) from thiophene solution (500 ppm) (190.5 ppm S). The adsorption process underwent a pseudo-second-order. Furthermore, the adsorption mechanism was studied. The results could be attributed to the partially replacing of the capping agent, i.e., tannic acid, with thiophene, which is considered a hydrophobic agent, during the agitation process. Accordingly, the silver nanoparticle, contami-nated with sulfur compounds, spontaneously migrated to the oil/water interface. AgNPs capped with thiophene were characterized using field emission-scanning electron microscope (FE-SEM), transmission electron micro-scope (HR-TEM), EDX-mapping, and dispersive Raman microscope. This approach provides a new way to remove thiophene by using the aqueous fluid of silver nanoparticles.

Automated summary

In this study, a simple and eco-friendly method was developed for the removal of thiophene from gasoline using water-based silver nanoparticles. The silver nanoparticles were prepared using tannic acid as a reducing and stabilizing agent, and their adsorption efficiency was evaluated. It was found that silver nanoparticles of size 8.3 +/- 2 nm showed the highest adsorption efficiency (88.4%) for thiophene. The adsorption process followed a pseudo-second-order kinetics, and the mechanism involved the displacement of tannic acid by thiophene. This approach provides a new way to remove thiophene using aqueous silver nanoparticles.