期刊
CATALYSIS TODAY
卷 257, 期 -, 页码 66-71出版社
ELSEVIER
DOI: 10.1016/j.cattod.2015.03.006
关键词
Cobalt spinel; Palladium; Methane; Oxidation; Combustion; Lean conditions
资金
- Italian Ministry of Education, University and Research [PRIN-2010XFT2BB]
- Executive Programme for Scientific and Technological Cooperation CANALETTO [M00478]
- Italian Republic (Ministry of Foreign Affairs)
- Republic of Poland (Ministry of Science and Higher Education)
In this work a series of palladium doped cobalt spinel catalysts was synthesized via solution combustion synthesis plus incipient wetness impregnation and tested in lean CH4 oxidation. The obtained catalysts were characterized from the structural and surface point of view (XRD, XRF, mu ARS, BET). The Pd doping level, calculated as PdO, ranged from 0.5 to 5 wt.%. The optimal palladium loading was determined on the basis of catalytic tests in gas mixtures containing from 0.5 to 2 vol.% of CH4. The temperature window for the catalytic activity of the Pd/Co3O4 materials spread from 270 to 550 degrees C. The optimal Pd loading was found to be 3 wt.%, and it was rationalized in terms of favorable surface Pd dispersion, since above this critical level of 3% an appreciable amount of PdO phase was formed. The reactivity of the optimal 3 wt.% Pd/Co3O4 catalyst from one-shot solution combustion synthesis was evaluated with the aim of optimizing the synthesis procedure. (C) 2015 Elsevier B.V. All rights reserved.
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