期刊
ADVANCED MATERIALS
卷 27, 期 33, 页码 4877-4882出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201405565
关键词
cracking; dealloying; inhibition; localized corrosion; self-assembled monolayers
类别
资金
- FWO Odysseus program [G0D0115N]
On self-assembled monolayer-covered Cu-Au substrates, localized volume shrinkage at initial dealloying sites leads to cracks within the attacked regions. It is started from well-controlled surface structures to gain fundamental insights in the driving mechanisms of localized corrosion and crack formation. Both the crack density and the crack morphology are critically dependent on surface orientation, crystallography, and inhibitor molecule species.
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