Exploring a novel silicone surfactant-based deep eutectic solvent functionalized magnetic iron particles for the extraction of organophosphorus pesticides in vegetable samples

The current study discussed the use of silicone surfactant-based deep eutectic solvent as a surface modifier for magnetic iron particles (Fe3O4) to produce a novel adsorbent and its application for the extraction of organophosphorus pesticides (OPPs) in vegetable samples. A deep eutectic solvent (DES) was prepared using low toxic and inexpensive substances such as silicone surfactant (SS) and dodecanoic acid (DoAc). This new eco-friendly SS:DoAc based DES was explored as a substitution to traditional organic reagents for surface modification of Fe3O4 to increase the adsorption capacity and to reduce the matrix interferences, hazardous waste generation and environmental pollution. The newly synthesized SS:DoAc@Fe3O4 adsorbent was successfully characterized and applied in magnetic solid phase extraction (MSPE). Under optimized conditions, the proposed approach exhibited excellent linearity ranging from 0.1 to 200 mu g/kg (R-2 >= 0.9970), low detection limit (0.03-0.1 mu g/kg) and acceptable relative recovery (80-119 %) for the studied OPPs.

Automated summary

The current study discusses the use of a silicone surfactant-based deep eutectic solvent as a surface modifier for magnetic iron particles to produce a novel adsorbent for the extraction of organophosphorus pesticides in vegetable samples. The new adsorbent shows improved adsorption capacity and can reduce matrix interferences and environmental pollution.