期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 26, 期 10, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202300090
关键词
cascade annulations; heating-induced; isothiocyanates; TFISYs; 2-trifluoromethyl quinolines
A heating-induced desulfurization annulation of CF3-imidoyl sulfoxonium ylides and isothiocyanates has been developed for the synthesis of 2-trifluoromethylquinolines. The reaction proceeds under metal- and additive-free conditions, providing various biologically valuable derivatives with high efficiency.
A heating-induced desulfurization annulation of readily available CF3-imidoyl sulfoxonium ylides and isothiocyanates for the construction of 2-trifluoromethylquinolines has been achieved. The developed transformation was performed under metal- and additive-free conditions, producing a variety of biologically valuable 2-trifluoromethylquinoline derivatives with high efficiency.
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