Role of tailing colloid from vanadium-titanium magnetite in the adsorption and cotransport with vanadium

The geochemical cycling of vanadium (V) in mining areas has attracted much attention. However, little knowledge was about the effects of tailing colloids on the fate and transport of vanadium in tailing reservoirs which was ignored before. This study investigated the interactions of tailing colloids from vanadium-titanium magnetite with vanadium. Colloid characterization, tailing leaching, adsorption, and column experiments of single and cotransport of tailing colloid with V were conducted. Results show that 98.08% V in the vanadium-titanium magnetite tailing was in the residual state with limited leachable V under various conditions. The adsorption of V to the tailing colloid was via electrostatic attraction and surface complexation on the heterogeneously distributed sorption sites on the colloid surface. The adsorption control step was the diffusion of V into the tailing colloid pores. The increase in pH and the decrease in ionic strength (IS) promoted the single transport of tailing colloid and V in quartz sand columns. In cotransport scenarios, V promoted the transport of tailing colloids via the surface coating effect. In contrast, the transport of V was retarded by the adsorbed tailing colloid on the quartz sand surface. The pre-adsorbed V in the column enhanced the subsequent transport of tailing colloids by electrical repulsion, while the pre-adsorbed tailing colloids facilitated the subsequent transport of V via cotransport of the released colloids with V. The high mobility of the tailing colloid and V and their cotransport in the porous media highly demonstrated the potential V pollution pathways that need to be taken into account.

Automated summary

The geochemical cycling of vanadium (V) in mining areas has been a popular topic, but the effects of tailing colloids on the fate and transport of vanadium in tailing reservoirs have been overlooked. This study investigated the interactions between tailing colloids and vanadium in vanadium-titanium magnetite tailings. The results showed that vanadium was mainly in the residual state in the tailings and its adsorption to the tailing colloid was primarily through electrostatic attraction and surface complexation. The mobility of tailing colloids and vanadium in the porous media demonstrated potential pollution pathways that need attention.