4.7 Article

FeCoP2 Nanoparticles Embedded in a Hybrid Carbon Matrix as a High Performance Bifunctional Catalyst of the Advanced Zinc-Air Battery

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Physical

Wheat straw as carbon source to prepare FeCoP2/N, P Dual-Doped carbon matrix as bifunctional catalyst for application in rechargeable Zinc-air and Aluminum-air batteries

Wendi Chen et al.

Summary: The transformation from crude wheat straw to efficient bifunctional catalysts resulted in a unique composite structure capable of catalyzing the oxygen reduction and evolution reactions. The catalyst exhibited impressive performances in metal-air batteries, with the liquid zinc-air battery achieving a power density of 122.5 mW cm(-2) and cycling for over 110 hours, while the solid-state zinc-air battery showed a power density of 55.6 mW cm(-2) and cycled for over 35 hours. Additionally, the catalyst showed excellent performances in aluminum-air batteries. This work has paved the way for preparing efficient metal-air battery catalysts from low-cost agricultural by-products.

APPLIED SURFACE SCIENCE (2022)

Article Engineering, Environmental

Multivalent CoSx coupled with N-doped CNTs/Ni as an advanced oxygen electrocatalyst for zinc-air batteries

Li-Na Lu et al.

Summary: This study demonstrates a hybrid composite catalyst consisting of CoSx nanoparticles, nitrogen-doped carbon nanotubes, and nickel, which shows enhanced electrocatalytic activity for oxygen reduction reaction and oxygen evolution reaction. The optimized hybrid catalyst exhibits excellent performance in an alkaline zinc-air battery, suggesting potential applications in sustainable energy conversion devices.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Multidisciplinary

An altered nanoemulsion assembly strategy for in-situ synthesis of Co2P/NP-C nanospheres as advanced oxygen reduction electrocatalyst for zinc-air batteries

Jing Shi et al.

Summary: The Co2P/NP-C catalyst synthesized using an altered nanoemulsion assembly approach exhibits excellent ORR electrocatalytic activity for metal-air batteries, with high half-wave potential and limiting current density comparable to commercial Pt/C. This performance is attributed to the in-situ formed Co2P nanoparticles and N, P heteroatoms in the carbon matrix, providing sufficient catalytic active sites and efficient mass/charge transport.

COMPOSITES PART B-ENGINEERING (2022)

Article Chemistry, Physical

Cobalt-doped basic iron phosphate as bifunctional electrocatalyst for long-life and high-power-density rechargeable zinc-air batteries

Lutao Song et al.

Summary: A novel micro-spherical cobalt-doped Fe5(PO4)4(OH)3 center dot H2O (Co-FPOH) was developed as an ORR/OER bifunctional electrocatalyst for rechargeable zinc-air batteries, showing superior performance compared to state-of-the-art RuO2. The ZAB assembled with Co-FPOH as an air electrode demonstrated an ultralong cycling lifetime, super high peak power density, and high discharge specific capacity at different current densities.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Energy & Fuels

Oxygen Defect-Enriched Hierarchical NiCo2O4 Hollow Rectangular Nanobars with Enhanced Bifunctional Oxygen Electrocatalysis for Efficient Rechargeable Zinc-Air Batteries

Kai -Lin Bao et al.

Summary: Hierarchical NiCo2O4 hollow rectangular nanobars (NiCo2O4 HRNBs) with ultrathin nanosheets were synthesized via template-directed methodology, exhibiting advanced features of hierarchical hollow nanoarchitecture and high surface area with abundant oxygen vacancies that accelerate oxygen reduction/evolution reaction kinetics. These NiCo2O4 HRNBs demonstrate outstanding bifunctional electrocatalytic performance and show potential for enhancing the performance of zinc-air batteries under alkaline electrolyte conditions.

ENERGY & FUELS (2022)

Article Chemistry, Applied

Metal-organic framework-derived carbon nanotubes with multi-active Fe-N/Fe sites as a bifunctional electrocatalyst for zinc-air battery

Chao Yang et al.

Summary: In this research, functional carbon nanotubes with multi-active sites were synthesized as an electrocatalyst for sustainable metal-air batteries, exhibiting superb bifunctional performance. The unique structure of the electrocatalyst was characterized using high-resolution synchrotron powder X-ray diffraction and X-ray absorption spectroscopy. The rechargeable zinc-air battery based on the electrocatalyst showed superior performance in terms of open-circuit voltage, power density, and cycling stability.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Energy & Fuels

Highly Efficient and Stable Bifunctional Electrocatalyst with Alloy/Oxide Heterostructures for a Rechargeable Zinc-Air Battery

Chang Rui et al.

Summary: Constructing heterogeneous interfaces between transition metal alloys and oxides in a carbon-based composite catalyst can enhance the efficiency of oxygen evolution reaction and oxygen reduction reaction (OER and ORR). In this study, a carbon-coated MnCoNi alloy/oxide catalyst (Ox-MnCoNi-C) was synthesized by carbonizing metal-organic frameworks (MOFs) and controllable reoxidation process. The Ox-MnCoNi-C catalyst exhibits excellent electrochemical performance due to the synergetic interaction between abundant active sites on the heterogeneous interface and the good electron transfer rate of graphitic carbon.

ENERGY & FUELS (2022)

Article Chemistry, Applied

FeCo alloy/N, S dual-doped carbon composite as a high-performance bifunctional catalyst in an advanced rechargeable zinc-air battery

Shengming Chang et al.

Summary: The FeCo/NSC composite, prepared via one-step carbonization, exhibits excellent ORR and OER catalytic performance for zinc-air batteries, promising a potential strategy for bifunctional electrocatalyst development.

JOURNAL OF ENERGY CHEMISTRY (2021)

Article Chemistry, Physical

N, P doped carbon nanotubes confined WN-Ni Mott-Schottky heterogeneous electrocatalyst for water splitting and rechargeable zinc-air batteries

Quan Zhang et al.

Summary: The novel trifunctional electrocatalyst WN-Ni@N,P-CNT exhibits Pt-like hydrogen evolution activity and superior oxygen evolution reaction activity, outperforming commercial IrO2 and Pt/C. This catalyst shows great potential for applications in water splitting and rechargeable zinc air batteries, with exceptional battery performance maintained over 330 hours.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

(Fe,Co)/N-Doped Multi-Walled Carbon Nanotubes as Efficient Bifunctional Electrocatalysts for Rechargeable Zinc-Air Batteries

Yugang Qi et al.

Summary: A highly efficient bifunctional oxygen electrode catalyst for zinc-air batteries has been successfully synthesized in this study, exhibiting superior performance and stability in charge-discharge cycles.

CHEMCATCHEM (2021)

Article Electrochemistry

Interfacial interaction between molybdenum phosphide and N, P co-doped hollow carbon fibers boosting the oxygen electrode reactions in zinc-air batteries

Miao He et al.

Summary: In this study, N and P co-doped hollow carbon fibers embedded with molybdenum phosphide nanoparticles were elaborately fabricated and used as novel bifunctional electrocatalysts to investigate the influence of interface interaction on oxygen electrode reactions in zinc-air batteries. Strong electron transfer at the interface between N, P-HCF and MoP NPs was realized, leading to improved catalytic activity and electrode reaction kinetics, resulting in enhanced power density and cycling performance of the rechargeable zinc-air batteries.

ELECTROCHIMICA ACTA (2021)

Article Electrochemistry

Mono-doped Carbon Nanofiber Aerogel as a High-Performance Electrode Material for Rechargeable Zinc-Air Batteries

Yiming Li et al.

Summary: An efficient oxygen electrocatalyst based on highly integrated carbon nanofiber and NPC aerogels demonstrates outstanding bifunctional performance. Density functional theory calculations reveal that active sites with multi-electrons weaken the O-O bond and facilitate oxygen reduction. The ZAB based on this aerogel exhibits good peak density and stable charge-discharge durability.

CHEMELECTROCHEM (2021)

Article Chemistry, Physical

Developing nitrogen and Co/Fe/Ni multi-doped carbon nanotubes as high-performance bifunctional catalyst for rechargeable zinc-air battery

Di Chen et al.

Summary: Innovative synthesis of multi-doped carbon nanotubes (CoFeNi@CNT) with metal-nitrogen-carbon and CoFeNi nanoparticles as dual-active-sites enables high performance in both oxygen reduction and oxygen evolution reactions, showing potential for rechargeable Zn-air batteries.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Physical

Self-Reconstruction of Co/Co2P Heterojunctions Confined in N-Doped Carbon Nanotubes for Zinc-Air Flow Batteries

Mingjie Wu et al.

Summary: The study presents a new strategy for fabricating Co/Co2P@NCNTs catalysts, with operando X-ray absorption spectroscopy and electrochemical measurements revealing the dynamic structural evolution of the catalyst during electrocatalytic operations. The self-reconstruction of the Co/Co2P heterojunctions into active CoOx(OH)(y) species is observed, contributing to outstanding ORR/OER activity and durability. The precatalyst shows high cycling stability in rechargeable zinc-air flow batteries.

ACS ENERGY LETTERS (2021)

Article Nanoscience & Nanotechnology

High-Quality CoFeP Nanocrystal/N, P Dual-Doped Carbon Composite as a Novel Bifunctional Electrocatalyst for Rechargeable Zn-Air Battery

Liang Gao et al.

Summary: The novel composite catalyst CoFeP@C with highly efficient bifunctional performance for catalyzing OER and ORR is ideal for rechargeable Zn-air batteries. The liquid Zn-air battery shows a large power density and stable charge and discharge cycles, while the solid-state Zn-air battery demonstrates stable operation for a duration of time. This work has advanced the understanding of synergistic catalysis and paved the way for high-performance bifunctional catalysts.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

N-Doped Carbon Nanotubes Derived from Graphene Oxide with Embedment of FeCo Nanoparticles as Bifunctional Air Electrode for Rechargeable Liquid and Flexible All-Solid-State Zinc-Air Batteries

Xiaoqiong Hao et al.

Summary: This work presents a novel synthesis method for efficient and durable bifunctional oxygen electrocatalysts, NPC/FeCo@NCNTs, which can be used for oxygen evolution and oxygen reduction reactions. The catalyst shows superior catalytic performance compared to other reported bifunctional catalysts, and can improve the performance of zinc-air batteries.

ADVANCED SCIENCE (2021)

Article Nanoscience & Nanotechnology

Zn, Co, and Fe Tridoped N-C Core-Shell Nanocages as the High-Efficiency Oxygen Reduction Reaction Electrocatalyst in Zinc-Air Batteries

Guang Li et al.

Summary: This study presents a facile and effective strategy to obtain highly efficient and stable transition metal-nitrogen-carbon (TM-N-C) nanomaterials as platinum-based substitutes for the oxygen reduction reaction (ORR) catalysts. By utilizing a multi-layer structure and multi-element co-doping, the material exhibits outstanding performance in 0.1M KOH, especially in terms of electrocatalysis and methanol tolerance.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Engineering, Environmental

Mn-based spinels evolved from layered manganese dioxides at mild temperature for the robust flexible quasi-solid-state zinc-air batteries

Bin Chen et al.

Summary: Flexible quasi-solid-state zinc-air batteries with outstanding power density, charge-discharge efficiency, and robustness are highly desired for wearable electronic devices. This study developed a two-step mild-temperature method to synthesize Mn-based spinels with remarkable oxygen catalytic activities. Additionally, a novel solid-state electrolyte with high ionic conductivity, water retention capability, and excellent tensile property was obtained by introducing cellulose into the polyacrylamide gel electrolyte.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Thermodynamics

Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries

Dongfang Chen et al.

Summary: The bifunctional electrocatalyst, Co3O4 with rich oxygen vacancies prepared on nickel foam and treated with carbon coating, shows improved catalytic activity and stability, leading to prolonged cycle life and increased power output of rechargeable zinc-air batteries.

ENERGY (2021)

Article Chemistry, Physical

Embedding Fe2P nanocrystals in bayberry-like N, P-enriched carbon nanospheres as excellent oxygen reduction electrocatalyst for zinc-air battery

Ruixiang Wang et al.

Summary: Transition metal phosphide/carbon composites, specifically Fe2P/NPCs, were successfully synthesized with N, P-enriched carbon nanospheres embedded with Fe2P nanocrystals. These composites exhibited outstanding electrocatalytic activity for the oxygen reduction reaction, high durability, and excellent methanol tolerance. Furthermore, when applied in zinc-air batteries, Fe2P/NPCs demonstrated superior performance compared to commercial Pt/C-based batteries.

JOURNAL OF POWER SOURCES (2021)

Article Chemistry, Multidisciplinary

FeCo Nanoparticles Encapsulated in N-Doped Carbon Nanotubes Coupled with Layered Double (Co, Fe) Hydroxide as an Efficient Bifunctional Catalyst for Rechargeable Zinc-Air Batteries

Tongrui Zhang et al.

Summary: The study presents an efficient catalyst consisting of FeCo nanoparticles embedded in N-doped carbon nanotubes for high ORR activity and excellent durability, with enhanced OER activity achieved through coupling with CoFe-layer double hydroxide. The air electrode using this catalyst exhibits high OCP, power density, and durability, showing promising practical applications for rechargeable zinc-air batteries.
Review Nanoscience & Nanotechnology

Recent Advances on MOF Derivatives for Non-Noble Metal Oxygen Electrocatalysts in Zinc-Air Batteries

Yuting Zhu et al.

Summary: MOF-derived non-noble metal-oxygen electrocatalysts play a crucial role in ZABs, and their performance is influenced by material structure. Research in this field mainly focuses on oxygen reduction and oxygen evolution reactions, with evolving catalyst design strategies aiming to enhance performance and address challenges.

NANO-MICRO LETTERS (2021)

Article Chemistry, Multidisciplinary

Surface Phosphorus-Induced CoO Coupling to Monolithic Carbon for Efficient Air Electrode of Quasi-Solid-State Zn-Air Batteries

Huan Liu et al.

Summary: The study introduces a surface phosphorization-monolithic strategy to embed CoO nanoparticles into paulownia carbon plate as monolithic electrodes for Zn-air batteries. The resulting electrode shows remarkable catalytic activity and long-term cycling stability in quasi-solid-state or aqueous ZABs.

ADVANCED SCIENCE (2021)

Article Nanoscience & Nanotechnology

Atomic Metal Vacancy Modulation of Single-Atom Dispersed Co/N/C for Highly Efficient and Stable Air Cathode

Sisi Liu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Engineering, Environmental

Phosphorus doped Co9S8@CS as an excellent air-electrode catalyst for zinc-air batteries

Wanqing Li et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Nanoscience & Nanotechnology

Plasma-Treated Ultrathin Ternary FePSe3 Nanosheets as a Bifunctional Electrocatalyst for Efficient Zinc-Air Batteries

Yanan Hao et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Multidisciplinary

Nitrogen-Doped Cobalt Pyrite Yolk-Shell Hollow Spheres for Long-Life Rechargeable Zn-Air Batteries

Xue Feng Lu et al.

ADVANCED SCIENCE (2020)

Article Nanoscience & Nanotechnology

Cu/S-Occupation Bifunctional Oxygen Catalysts for Advanced Rechargeable Zinc-Air Batteries

Xu Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Physical

Cu97P3-x-yOxNy/NPC as a bifunctional electrocatalyst for rechargeable zinc-air battery

Bing Yuan et al.

JOURNAL OF POWER SOURCES (2019)

Article Chemistry, Multidisciplinary

Recent Progress in Electrically Rechargeable Zinc-Air Batteries

Jing Fu et al.

ADVANCED MATERIALS (2019)

Article Chemistry, Multidisciplinary

Electrically Rechargeable Zinc-Air Batteries: Progress, Challenges, and Perspectives

Jing Fu et al.

ADVANCED MATERIALS (2017)