期刊
ENERGY
卷 261, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2022.125220
关键词
natural Gas hydrate; Temperature gradient; Heat transfer; Thermodynamic
资金
- National Key Research and Development Plan of China [2021YFC2800902]
- National Nat-ural Science Foundation of China [51822603, U19B2005]
- Fundamental Research Funds for the Central Universities of China [DUT21ZD103]
- Liao Ning Revitalization Talents Program [XLYC1907096]
This study simulated methane hydrate sediment with a temperature gradient and found that the temperature gradient affects the formation and dissociation of hydrates. The results of this study are significant for improving the efficiency of methane hydrate exploitation.
Commercial exploitation of methane hydrate has become an essential potential to issue global energy shortage. Yet, the temperature gradient of hydrate sediments is always ignored, and laboratory-scale methane hydrate formation and dissociation investigations with temperature gradient are rarely conducted. In this study, a 240 mm height reactor was used to simulate hydrate sediment with the temperature gradient of approximately 0.026 degrees C/mm in height. Methane hydrates were first formed under constant-volume condition with three initial pressures of 6, 8 and 10 MPa. The presence of temperature gradient caused the difference in the height of hydrate-bearing region, and the height expanded with formation pressure. Then, the hydrates were dissociated by depressurization to 2.5 MPa in three production rates of 0.1, 2.3 and 60 ln/min. The temperature changes of hydrate-bearing and non-hydrate areas were obviously distinguished, affected by hydrate dissociation. Due to the limited heat transfer, an isothermal period at approximately 1 degrees C, irrelevant to the temperature gradient, was observed during the dissociation process at 2.5 MPa. After comparing with the natural warming trajectory, it is confirmed that the temperature response of hydrate-bearing sediments agrees with thermodynamic relationship, rather than conventional heat transfer. These results are significant for the efficiency improvement of actual methane hydrate exploitation.
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