4.5 Article

The Control of Shale Composition on the Pore Structure Characteristics of Lacustrine Shales: A Case Study of the Chang 7 Member of the Triassic Yanchang Formation, Ordos Basin, North China

期刊

ENERGIES
卷 15, 期 22, 页码 -

出版社

MDPI
DOI: 10.3390/en15228353

关键词

shale pore structure; mineralogical composition; clay minerals; organic matter; lacustrine shales; Yanchang formation

资金

  1. State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development (Sinopec) [33550000-21-ZC0613-0325]
  2. National Science Foundation of China [42102194, 42202167]

向作者/读者索取更多资源

The pore structure characteristics of lacustrine shales are controlled by different components, including minerals and organic matter. Clay minerals primarily control the mesopore characteristics of the shales and the micropore characteristics of organic-lean shales, while both clay minerals and organic matter control the micropore characteristics of organic-rich samples. The study provides important insights into the compositional control on the pore structure characteristics of lacustrine shales.
The pore structure characteristics of shales are controlled by their mineral and organic matter compositions. However, the contributions of different components to the pore structure characteristics of lacustrine shales remain poorly understood. In this study, fifteen Chang 7 Member shales of the Yanchang Formation, Ordos Basin, were investigated through total organic carbon (TOC), X-ray diffraction (XRD), scanning electron microscopy (SEM), and low-pressure N-2 and CO2 adsorption analyses to study the control of shale composition on the pore structure characteristics of lacustrine shales. The results show that the average TOC content of the Chang 7 Member shales is 9.63 wt.%. XRD analysis shows that minerals in the Chang 7 Member shales consist of quartz, feldspars, clay minerals, and pyrite. The clay minerals were dominated by illite, chlorite, and interstratified illite/smectite. The mesopore characteristics of the Chang 7 Member shales and micropore characteristics of organic-lean shales are mainly controlled by clay minerals, whereas the micropore characteristics of organic-rich samples are controlled by both clay minerals and organic matter. SEM observations show that the phyllosilicate framework pores are the main pore type in the Chang 7 Member shales. The results of this study provide important insights into compositional control on the pore structure characteristics of lacustrine shales.

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