SrFe1-xZrxO3-δ perovskite oxides as negative electrodes for supercapacitors

Recently, perovskite oxides have been considered as promising positive electrode materials for supercapacitor applications because of their high theoretical capacitance. However, few research about using perovskite oxides as negative materials has been done up to now. Herein, a series of SrFe1-xZrxO3-delta (0 <= x <= 0.20) oxides were synthesized as supercapacitor negative electrodes by facile solid-state reaction method for the first time. The effects on oxygen vacancies, structural stability and electrochemical performance of SrFe1-xZrxO3-delta after Zr substituting were fully investigated. One of the key conclusions of the present study is that, introducing Zr into SrFeO3-delta results in a effective increase of oxygen vacancy, which significantly improves the charge storage ca-pacity of the as-prepared electrode. Besides, Zr substitution is beneficial to improve the structural stability compared with pure SrFeO3-delta. It has been found that SrFe0.85Zr0.15O3-delta@Carbon Cloth (CC) electrode displays the best electrochemical property. At a current density of 0.5 A g-1, the electrode delivers a specific capacitance up to 163.92 F g-1, and is considered as a promising negative electrode. In addition, the maximum energy density can achieve to 7.6 Wh kg- 1 at a power density of 2.0 kW kg- 1 for the asymmetric supercapacitor MnO2@CC// SrFe0.85Zr0.15O3-delta@CC. Overall, a certain contribution to the research and development of perovskite oxides as supercapacitornegative materials has been made in the present work. The results indicate that SrFe0.85Zr0.15O3-delta perovskite presents potential development prospect in the field of hybrid supercapacitor and further optima-zation is expected.

Automated summary

In this study, a series of SrFe1-xZrxO3-delta (0≤x≤0.20) oxides were synthesized as supercapacitor negative electrodes for the first time. It was found that introducing Zr effectively increased the oxygen vacancy in SrFeO3-delta, significantly improving the charge storage capacity of the electrode, and it also improved the structural stability. Among them, SrFe0.85Zr0.15O3-delta@Carbon Cloth electrode exhibited the best electrochemical performance.