4.5 Review

Recent advances in layered double hydroxides-based electrochemical sensors: Insight in transition metal contribution

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Summary: Metal-organic frameworks (MOFs) are porous coordination polymers synthesized by metal-based nodes and organic linkers, known for their versatile properties. This review discusses the use of MOFs as electrochemical sensors and how they enhance the selectivity and sensitivity of the sensors, particularly in detecting heavy metal ions and organic pollutants from groundwater and water bodies. Additionally, the review explores the detection of various compounds like antibiotics, phenolic compounds, and pesticides using MOFs, as well as the potential of metal nano-particles and metal-oxide based composites for sensing applications. It also highlights the challenges and future opportunities in the field of MOF-based electrochemical sensors.

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Binder free 3D core-shell NiFe layered double hydroxide (LDH) nanosheets (NSs) supported on Cu foam as a highly efficient non-enzymatic glucose sensor

Nasir Rafique et al.

Summary: In this study, a three-dimensional hierarchical core-shell catalyst was used as a non-enzymatic glucose sensing electrode, demonstrating higher sensitivity, lower limit of detection, and wider linear range. The sensor exhibited excellent stability, reproducibility, and interference ability, and showed high practicality in real environment.

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Plasma-Assisted Fabrication of Molecularly Imprinted NiAl-LDH Layer on Ni Nanorod Arrays for Glyphosate Detection

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Summary: An inorganic-framework molecularly imprinted NiAl layered double hydroxide was prepared on Ni nanorod arrays with specific recognition ability for glyphosate pesticide. The electrode exhibited enhanced sensitivity and selectivity, with linear current response to glyphosate concentration and a low limit of detection. The electrocatalytic oxidation mechanism and the impact of molecular imprinting on the electrode performance were investigated.

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Recent trends in layered double hydroxides based electrochemical and optical (bio)sensors for screening of emerging pharmaceutical compounds

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Non-enzymatic H2O2 electrochemical sensor based on NiAl-LDH/PPy-Ag composite

Kai Zhang et al.

Summary: This study developed a novel strategy to prepare a non-enzymatic H2O2 sensor using Ag nanoparticles. The LDH/PPy-Ag electrode material exhibited high stability and excellent electrocatalytic activity for H2O2 reduction. The sensor showed excellent sensing performance towards H2O2, with a wide linear range, high sensitivity, low detection limit, and good stability.

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Summary: With the energy crisis and environmental pollution worsening, it is urgent to develop renewable and clean energy sources. Layered double hydroxides (LDHs) supporting noble metal catalysts show remarkable catalytic activity and good stability in electrolyzing water to produce hydrogen, demonstrating promising applications in the field.

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Evaluation of hierarchical glucose oxidase/Co3Mn-CO3 LDH modified electrodes for glucose detection

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Summary: A glucose amperometric biosensor and a 3D porous bioelectrode were prepared for sensitive detection of glucose. The biosensor was constructed by multilayer deposition of Co3Mn-CO3 layered double hydroxide, glucose oxidase, and carrageenan on a glassy carbon electrode, while the bioelectrode was fabricated by impregnation of carbon felt with Co3Mn-CO3 nanoparticles and glucose oxidase. The sensitivity and detection limit were determined to be 12.8 mA M-1 cm(-2) and 0.02 mM, respectively, showing promising results for glucose detection.

ELECTROCHIMICA ACTA (2021)

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Synthesis and Characterization of Layered Double Hydroxides as Materials for Electrocatalytic Applications

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NANOMATERIALS (2021)

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NiCo-LDH nanoflake arrays-supported Au nanoparticles on copper foam as a highly sensitive electrochemical non-enzymatic glucose sensor

Mao Shen et al.

Summary: A novel electrochemical non-enzymatic glucose sensor, NiCo-LDH@Au/Cu electrode, was successfully fabricated with high electrocatalytic activity for glucose oxidation. The sensor exhibited a wide linear range, low detection limit, ultra-prompt response time, high sensitivity, good selectivity, and stability, making it a promising candidate for glucose detection in human serum.

ANALYTICA CHIMICA ACTA (2021)

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Layer double hydroxides (LDHs)- based electrochemical and optical sensing assessments for quantification and identification of heavy metals in water and environment samples: A review of status and prospects

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Summary: Heavy metal contamination is a severe environmental issue, and efforts have been made to develop sensors for monitoring the environment. Incorporating nanoparticles and nanostructures into sensors significantly enhances sensitivity, selectivity, and multiplexed detection ability. Layered double hydroxides (LDHs) have gained attention in analytical chemistry due to their benefits, but are still restricted in certain applications.

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A review on electrochemical biosensing platform based on layered double hydroxides for small molecule biomarkers determination

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Glyphosate and glufosinate detection at electrogenerated NiAl-LDH thin films

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Exciting new directions in the intersection of functionalized sol-gel materials with electrochemistry

A Walcarius et al.

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Sensors and biosensors based on clay-modified electrodes - new trends

C Mousty

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Clay modified electrodes:: Present applications and prospects

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Electrochemical applications of silica-based organic-inorganic hybrid materials

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