4.7 Article

Multifaceted role of silver salts as ligand scavengers and different behavior of nickel and palladium complexes: beyond halide abstraction

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

A different polynorbornene backbone by combination of two polymer growth pathways: vinylic addition and ring opening via β-C elimination

Ignacio Perez-Ortega et al.

Summary: A new polynorbornene skeleton has been discovered, synthesized using a nickel catalyst and controlled ligand coordination ability. The backbone structure is formed through vinylic addition polymerization and β-C elimination, and can be modulated by ligand coordination.

CHEMICAL SCIENCE (2022)

Review Chemistry, Multidisciplinary

Nickel-Catalyzed Reductive Carboxylation and Amidation Reactions

Andreu Tortajada et al.

Summary: In recent years, considerable progress has been made in Ni-catalyzed reductive carboxylation and amidation reactions utilizing carbon dioxide and isocyanate counterparts, allowing the synthesis of carboxylic acids and amides. The utilization of nickel catalysts enables the use of less reactive and less-polarized counterparts for the formations of these functional groups, expanding the possibilities in synthetic chemistry.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Review Chemistry, Multidisciplinary

Nickel-Catalyzed C-Heteroatom Cross-Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination

Chen Zhu et al.

Summary: The formation of C-heteroatom bonds through recent advances in homo- and heterogeneous Ni-catalyzed reactions under mild conditions is attractive due to sustainability and practicability. The generation of Ni-III and excited Ni-II intermediates enables mild cross-couplings, leading to the development of various catalytic systems involving photoredox and nickel dual catalysis, photoexcited nickel catalysis, electro and nickel dual catalysis, and heterogeneous photoredox and nickel dual catalysis using different materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Direct and Enantioselective Aldol Reactions Catalyzed by Chiral Nickel(II) Complexes

Stuart C. D. Kennington et al.

Summary: A direct and asymmetric aldol reaction of N-acyl thiazinanethiones with aromatic aldehydes catalyzed by chiral nickel(II) complexes was reported. The reaction gives high yields of O-TIPS-protected anti-aldol adducts with remarkable stereocontrol and atom economy. The removal of the achiral scaffold provides enantiomerically pure intermediates with synthetic interest for producing anti-alpha-amino-beta-hydroxy and alpha,beta-dihydroxy carboxylic derivatives, with theoretical calculations explaining the observed high stereocontrol.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Deciphering the Role of Silver in Palladium-Catalyzed C-H Functionalizations

Trisha Bhattacharya et al.

Summary: Silver salts play a crucial role in palladium-catalyzed C-H functionalization, beyond just acting as an oxidant. The bimetallic couple's low energy route outperforms monometallic catalysis, with computational studies supporting electronic relay between the two metal species. This perspective aims to unveil the various aspects of silver salts in Pd-catalyzed C-H activation, challenging the misconception of silver solely as an oxidant.

ACS CATALYSIS (2021)

Article Multidisciplinary Sciences

Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki-Miyaura cross-coupling

Yuqiang Li et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Physical

Ag/Pd Cocatalyzed Direct Arylation of Fluoroarene Derivatives with Aryl Bromides

Adyasha Panigrahi et al.

ACS CATALYSIS (2020)

Review Chemistry, Multidisciplinary

Mechanisms of Nickel-Catalyzed Coupling Reactions and Applications in Alkene Functionalization

Justin Diccianni et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

Review Chemistry, Multidisciplinary

Emerging Palladium and Nickel Catalysts for Copolymerization of Olefins with Polar Monomers

Chen Tan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Chemistry, Multidisciplinary

3d Transition Metals for C-H Activation

Parthasarathy Gandeepan et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Inorganic & Nuclear

Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future

Louis-Charles Campeau et al.

ORGANOMETALLICS (2019)

Article Chemistry, Inorganic & Nuclear

Multiple roles of silver salts in palladium-catalyzed C-H activations

Katherine L. Bay et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2018)

Article Chemistry, Inorganic & Nuclear

Bench-Stable Nickel Precatalysts with Heck-type Activation

Jessica M. Weber et al.

ORGANOMETALLICS (2018)

Article Chemistry, Inorganic & Nuclear

Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C-H Functionalization Reactions

Monica D. Lotz et al.

ORGANOMETALLICS (2017)

Article Chemistry, Multidisciplinary

Ag(I)-Catalyzed C-H Activation: The Role of the Ag(I) Salt in Pd/Ag-Mediated C-H Arylation of Electron-Deficient Arenes

Daniel Whitaker et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Non-innocent Additives in a Palladium(II)-Catalyzed C-H Bond Activation Reaction: Insights into Multimetallic Active Catalysts

Megha Anand et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

Synthesis of Functional Polyolefins Using Cationic Bisphosphine Monoxide-Palladium Complexes

Brad P. Carrow et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Inorganic & Nuclear

Palladium catalysts for norbornene polymerization. A study by NMR and calorimetric methods

Juan A. Casares et al.

ORGANOMETALLICS (2008)

Article Chemistry, Multidisciplinary

Ortho arylation of acetanilides via Pd(II)-catalyzed C-H functionalization

Shangdong Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)