4.7 Article

Construction of High-Performance Energetic MOFs: C4N8O42-and C3N4O42-with Their Derivatives, Compared with Their Energetic Salts

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Engineering, Environmental

Intramolecular integration of multiple heterocyclic skeletons for energetic materials with enhanced energy & safety

Tingou Yan et al.

Summary: This study focuses on the development of new generations of high explosives with superior overall performance, by intramolecular integration of different heterocyclic skeletons. An advanced energetic molecule was designed and prepared, showing comparable energy level to RDX but with significantly better safety properties. Quantum chemistry methods were employed to further investigate the sensitivities and thermal stabilities, indicating the potential for accelerating the development of advanced energetic materials.

CHEMICAL ENGINEERING JOURNAL (2022)

Editorial Material Engineering, Environmental

Introduction of energetic bis-1,2,4-triazoles bridges: A strategy towards advanced heat resistant explosives

Tingou Yan et al.

Summary: This study successfully developed a novel heat-resistant compound BPT-2 with ultrahigh thermal stability and enhanced energy level, and revealed the significant impact of bis-1,2,4-triazoles on thermal stability.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Salt Formation, to Realize a Good Combination of High Energy and Low Sensitivity of Nitroform-Based Energetic Compounds

Feng Yang et al.

Summary: A series of energetic salts with nitroform structures were synthesized and fully characterized by X-ray single-crystal diffraction. They exhibited excellent detonation performance, high specific impulse, and low sensitivity to mechanical stimuli. The relationship between molecular structure and sensitivity was explored, revealing a decrease in sensitivity after salt formation.

CRYSTAL GROWTH & DESIGN (2022)

Article Chemistry, Inorganic & Nuclear

Lithium Nitropyrazolates as Potential Red Pyrotechnic Colorants

Alicia M. W. Dufter-Munster et al.

Summary: Strontium-based red pyrotechnic colorants have lost their reputation due to the harmful effects on adolescents. In search of replacements, researchers have utilized the energetic properties, safety, and combustion behavior of nitropyrazoles to design corresponding lithiated materials. Extensive characterization and assessment of these materials were conducted to evaluate their potential as alternatives.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2022)

Article Chemistry, Inorganic & Nuclear

Tetrazole-Based Energetic Metal-Organic Frameworks: Impacts of Metals and Ligands on Explosive Properties

Sujee Cho et al.

Summary: The study introduces two energetic metal-organic frameworks with unique detonation and sensitivity properties, showing potential for the development of new energetic materials.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2022)

Article Engineering, Environmental

Simple reaction to prepare a heat-resistant and insensitive explosive (2-nitro-[1,2,4]triazolo[1,5-a][1,3,5]triazine-5,7-diamine) and its derivatives

Yuteng Cao et al.

Summary: In this study, a novel 5,6-fused energetic molecule NTTD was designed and easily obtained. By introducing oxidants and high energy groups, derivatives of NTTD were prepared with good comprehensive properties. NTTD exhibited excellent thermostability and low mechanical sensitivities. The whole preparation process had advantages of simple operation, short time, cheap and simple reagents, good repeatability, and high yield, indicating its potential as a heat-resistant and insensitive explosive candidate.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

High performance and heat-resistant pyrazole-1,2,4-triazole energetic materials: Tuning the thermal stability by asymmetric framework and azo-bistriazole bridge

Jinxiong Cai et al.

Summary: Driven by the increasing application of thermal stable explosives in industries like deep mining and aerospace, the search for heat-resistant energetic materials with high-energy level has gained significant attention. In this study, two advanced heat-resistant explosives were synthesized using straightforward methods, and they showed excellent thermal decomposition temperature and energy properties, making them promising candidates for advanced heat-resistant explosives.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Organic

From Nitro- to Heterocycle-Functionalized 1,2,4-Triazol-3-one Derivatives: Achieving High-Performance Insensitive Energetic Compounds

Yuji Liu et al.

Summary: In this study, a mild and efficient method for synthesizing 5-nitro-1,2,4-triazol-3-one (TO) was reported. The synthesized compounds were fully characterized and one of them (Compound 2) showed promising properties as a high-performance insensitive energetic material.

JOURNAL OF ORGANIC CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

A novel energetic nickel coordination compound based on carbohydrazide and dinitramide

Sergey G. Il'yasov et al.

Summary: In this study, Dinitramide was reacted with carbohydrazide to produce mono- and bis-substituted salts. The reaction of the nickel salt of dinitramide with carbohydrazide resulted in the formation of a coordination compound, tris(carbohydrazide-N,O)nickel(II) bis-dinitramide, whose crystal structure was determined by X-ray diffraction.

MENDELEEV COMMUNICATIONS (2022)

Article Chemistry, Organic

1,3,5-Tris[(2H-tetrazol-5-yl)methyl]isocyanurate and Its Tricationic Salts as Thermostable and Insensitive Energetic Materials

Parasar Kumar et al.

Summary: Various energetic salts were obtained from inexpensive starting materials via a simple and efficient synthetic route. These compounds showed excellent detonation properties, high nitrogen content, high positive heats of formation, good thermostability, and remarkable insensitivity.

ORGANIC LETTERS (2022)

Article Chemistry, Physical

Impact of regiochemistry on thermal stability of trifuroxan based energetic materials: A theoretical perspective

Meiheng Lv et al.

Summary: This study thoroughly investigates the impact of regioisomerism on the thermal stability of two trifuroxan based energetic regioisomers (BFTF-1 and BFTF-2). The primary decomposition path for both regioisomers is determined to be NO2-dissociation according to the Gibbs free energy profiles. The different thermal stabilities of BFTF-1 and BFTF-2 can be explained by the difference in energy and the evaluation of intramolecular interactions and electron effects.

COMPUTATIONAL AND THEORETICAL CHEMISTRY (2022)

Article Nanoscience & Nanotechnology

Access to Green Pyrotechnic Compositions via Constructing Coordination Polymers: A New Approach to the Application of 3,4-Dinitropyrazole

Wenli Cao et al.

Summary: In this study, alkali and alkaline-earth metal salts with 3,4-dinitropyrazole (DNP) were synthesized and fully characterized. The salts showed satisfactory thermal stabilities and the presence of crystallized water in certain structures. Burning and pyrotechnic tests suggested that some of these salts could be promising candidates for application in green pyrotechnics.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Chemistry, Physical

The role of regioisomerism on thermal stability of furoxan based energetic materials

Meiheng Lv et al.

Summary: This study thoroughly investigates the effects of regioisomerism on the thermal stabilities of furoxan-based energetic materials and discusses their initial decomposition mechanisms. An unusual transition state is found in the products, which is attributed to the strong weak interaction between the dissociation products.

JOURNAL OF MOLECULAR STRUCTURE (2022)

Article Chemistry, Multidisciplinary

Searching for high performance asymmetrically substituted teterazine energetic materials based on 3-hydrazino-6-(1H-1,2,3,4-tetrazol-5-ylimino)-s- tetrazine

Xiang Chen et al.

Summary: In this study, a series of teterazine energetic materials were synthesized using 3-hydrazino-6-(1H-1,2,3,4-tetrazol-5-ylimino)-s-tetrazine as the precursor. The obtained compounds were characterized and evaluated for their thermal dynamics, detonation properties, and impact sensitivities. Compounds 15-17 exhibited excellent energetic properties and comparable or lower impact sensitivities than RDX, making them promising candidates for high-performance secondary explosives or insensitive energetic materials.

ARABIAN JOURNAL OF CHEMISTRY (2022)

Article Engineering, Environmental

Power of sulfur-Chemistry, properties, laser ignition and theoretical studies of energetic perchlorate-free 1,3,4-thiadiazole nitramines

Jagadish Das et al.

Summary: The chemistry of lead-, azide- and perchlorate-free photosensitive energetic materials is an emerging field of research with wide applications. In this study, new sulfur-containing energetic molecules were designed, synthesized, and their properties were studied. These molecules showed good thermostability and brisance, and one of them exhibited laser igniting properties. Extensive calculations were performed to study the laser ignition mechanism.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Highly energetic salts based on the planar 3,6-dinitramino[1,2,4]triazolo[4,3-b][1,2,4]triazole

Chengming Bian et al.

Summary: A new series of energetic salts based on all-carbon-nitramino-functionalized fused-triazole backbone were synthesized, exhibiting good thermostability and lower sensitivity. These salts possess fascinating detonation velocities and acceptable stabilities, making them competitive high-energy-density materials.

JOURNAL OF MOLECULAR STRUCTURE (2022)

Article Chemistry, Inorganic & Nuclear

Syntheses and Characterization of two cyclo-pentazolate salts

Xieyang Wang et al.

Summary: Two energetic cyclo-N-5(-) salts were synthesized in this study, showing good thermal stability with detonation velocities around 7400 m s(-1) and low mechanical sensitivity. This work enriches the cyclo-pentazolate salts system, facilitating the exploration of more heat-resistant and higher detonation velocities pentazolate salts.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2021)

Review Chemistry, Multidisciplinary

Development and Evolution of Energetic Cocrystals

Jonathan C. Bennion et al.

Summary: This article discusses the impact of cocrystallization on the performance, sensitivity to external stimuli, and manufacturability of energetic materials, as well as the motivating effect of cocrystallization on the exploration of novel materials. Cocrystallization combines widely used energetic materials with nonenergetic coformers to alter key properties.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Review Chemistry, Multidisciplinary

Tetrazoles via Multicomponent Reactions

Constantinos G. Neochoritis et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Inorganic & Nuclear

Energetic Metal-Organic Frameworks Incorporating NH3OH+ for New High-Energy-Density Materials

Yongan Feng et al.

INORGANIC CHEMISTRY (2019)

Article Nanoscience & Nanotechnology

Framework-Interpenetrated Nitrogen-Rich Zn(II) Metal-Organic Frameworks for Energetic Materials

Jian-Di Lin et al.

ACS APPLIED NANO MATERIALS (2019)

Article Chemistry, Applied

Effect of Bonding Agent on the Mechanical Properties of GAP High-Energy Propellant

Jingke Deng et al.

PROPELLANTS EXPLOSIVES PYROTECHNICS (2017)

Article Multidisciplinary Sciences

A promising high-energy-density material

Wenquan Zhang et al.

NATURE COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

Azido and Tetrazolo 1,2,4,5-Tetrazine N-Oxides

David E. Chavez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Potassium 4,4′-Bis(dinitromethyl)-3,3′-azofurazanate: A Highly Energetic 3D Metal-Organic Framework as a Promising Primary Explosive

Yongxing Tang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Coordination Polymers with High Energy Density: An Emerging Class of Explosives

Kyle A. McDonald et al.

CRYSTAL GROWTH & DESIGN (2015)

Review Chemistry, Multidisciplinary

Energetic Ionic Liquids as Explosives and Propellant Fuels: A New Journey of Ionic Liquid Chemistry

Qinghua Zhang et al.

CHEMICAL REVIEWS (2014)

Article Chemistry, Physical

On the Decomposition Mechanisms of New Imidazole-Based Energetic Materials

Zijun Yu et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2013)

Article Chemistry, Multidisciplinary

Multiwfn: A multifunctional wavefunction analyzer

Tian Lu et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2012)

Article Biochemical Research Methods

Quantitative analysis of molecular surface based on improved Marching Tetrahedra algorithm

Tian Lu et al.

JOURNAL OF MOLECULAR GRAPHICS & MODELLING (2012)

Article Chemistry, Multidisciplinary

Ionic Polymers as a New Structural Motif for High-Energy-Density Materials

Oleksandr S. Bushuyev et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Improved Stability and Smart-Material Functionality Realized in an Energetic Cocrystal

Onas Bolton et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Review Chemistry, Multidisciplinary

Azole-Based Energetic Salts

Haixiang Gao et al.

CHEMICAL REVIEWS (2011)