4.7 Article

Revealing corrosion parameters of steel in alkali-activated materials

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CORROSION SCIENCE
卷 210, 期 -, 页码 -

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2022.110849

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Alkali -activated material; Corrosion; Chloride; EIS; Tafel

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The long-term corrosion behavior of reinforcing steel in alkali-activated mortars (AAMs) with different binder compositions was studied over a 360-day period. Electrochemical techniques were used to determine corrosion potential, polarisation resistance, and Tafel slopes. The study proposes new limits for passive and active corrosion in AAMs based on the time evolution of corrosion parameters.
The long-term corrosion behaviour of reinforcing steel embedded in alkali-activated mortars (AAMs) prepared with three different binder compositions was monitored over a 360-day period by cyclic wetting/drying and spraying with chloride solution. Corrosion potential and polarisation resistance were determined by linear polarisation, individual resistance of mortar and steel by electrochemical impedance spectroscopy, and Tafel slopes by potentiodynamic anodic polarisation. The results were validated by correlating the electrochemical mass losses with the gravimetric mass losses. Based on the time evolution of the corrosion parameters, the study proposes new limits for passive and active corrosion conditions for reinforcing steel in AAMs.

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