☆ 4.8 Review

Understanding the unceasing evolution of Co(II) based single-ion magnets

COORDINATION CHEMISTRY REVIEWS (2023)

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Article Chemistry, Inorganic & Nuclear

Role of Coordination Geometry on the Magnetic Relaxation Dynamics of Isomeric Five-Coordinate Low-Spin Co(II) Complexes

Lena Spillecke et al.

Summary: Two geometric isomers of a five-coordinate low-spin Co(II) complex were synthesized and characterized, revealing the influence of coordination geometry on magnetization relaxation dynamics. The relaxation times were found to be significantly different between the isomers, with the change attributed to g-anisotropy and spatial arrangement of ligands around the Co(II) ions. Experimental observations were supported by theoretical calculations.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Inorganic & Nuclear

Pentacoordinate cobalt(II) single ion magnets with pendant alkyl chains: shall we go for chloride or bromide?

Jana Jurakova et al.

Summary: Four pentacoordinate complexes have been synthesized and their structures determined. The magnetic properties of the compounds were investigated, and the relationship between geometry and orbital ordering was discussed. Theoretical calculations were in good agreement with experimental data. Wet lithographic technique was used to evaluate the processability of the complexes and the preparation of microstructured films.

INORGANIC CHEMISTRY FRONTIERS (2022)

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Article Chemistry, Inorganic & Nuclear

Hydrogen-Bonded Framework of a Cobalt(II) Complex Showing Superior Stability and Field-Induced Slow Magnetic Relaxation

Dong Shao et al.

Summary: A unique hydrogen-bonded organic-inorganic framework with superior thermal and chemical stability and permanent porosity was constructed. Magnetic studies revealed significant magnetic anisotropy and field-induced slow magnetic relaxation in the framework. Computational studies provided insights into the origin of the magnetic anisotropy.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Inorganic & Nuclear

Self-assembly of fish-bone and grid-like CoII-based single-molecule magnets using dihydrazone ligands with NNN and NNO pockets

Qianqian Yang et al.

Summary: Three different Co-II complexes with unique structures were synthesized by self-assembly methods. Magnetic susceptibility measurements and theoretical calculations revealed their magnetic properties.

DALTON TRANSACTIONS (2022)

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Review Chemistry, Multidisciplinary

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

Yan-Cong Chen et al.

Summary: This perspective explores the delicately coupled spin system of Single-Molecule Magnets (SMMs) between multiple spin centers, presenting hierarchical couplings from intra-atomic to intra-molecular to inter-molecular, and discussing their impacts on energy level structures and magnetic behaviors, proposing a promising big picture for further development in molecular magnetism.

CHEMICAL SCIENCE (2022)

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Article Chemistry, Inorganic & Nuclear

Slow magnetic relaxation for cobalt(II) complexes in axial bipyramidal environment: an S=1/2 spin case

Evangelos Pilichos et al.

Summary: A new family of mononuclear cobalt(II) complexes with nickel(II) and copper(II) has been studied, and some members of this family exhibit field-induced slow relaxation of magnetization. Ultra-low frequency Raman spectroscopy has been used to understand the relationship between slow relaxation and lattice vibrations.

DALTON TRANSACTIONS (2022)

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Article Chemistry, Inorganic & Nuclear

Magnetic anisotropy of two tetrahedral Co(II)-halide complexes with triphenylphosphine ligands

Wei Lv et al.

Summary: Recently, the influence of ligand choice and geometric control on the magnetic properties of mononuclear Co(II) complexes has been studied. The results show that the coordination environment plays a significant role in the magnetic relaxation behavior of the complexes.

DALTON TRANSACTIONS (2022)

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Article Chemistry, Inorganic & Nuclear

Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt(II) complexes with zero-field hidden single-molecule magnet behaviour: the important rote of the distortion of the coordination sphere and intermolecular interactions in the stow relaxation

Aritz Landart-Gereka et al.

Summary: The structures and magnetic properties of a series of complexes were studied using various techniques, revealing the influence of counteranion on the coordination environment and different magnetic behaviors of the complexes. These findings are important for a better understanding of the properties of these complexes.

INORGANIC CHEMISTRY FRONTIERS (2022)

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Article Chemistry, Inorganic & Nuclear

Field-induced mononuclear cobalt(II) single-molecule magnet (SMM) based on a benzothiadiazole-ortho-vanillin ligand

Nataliya Plyuta et al.

Summary: In this study, a unique π-conjugated molecule was synthesized, which showed high coordination distortion of the central metal and a novel multi-electron-state transport behavior. In addition, the molecule exhibited slow relaxation of magnetization, indicating its potential application value.

DALTON TRANSACTIONS (2022)

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Article Chemistry, Inorganic & Nuclear

Iron(II), Cobalt(II), and Nickel(II) Complexes of Bis(sulfonamido)benzenes: Redox Properties, Large Zero-Field Splittings, and Single-Ion Magnets

Heiko Bamberger et al.

Summary: Metal complexes with 1,2-bis(sulfonamido)benzene ligands were synthesized and investigated for their high zero-field splitting (ZFS) and potential single-ion magnet properties. The cobalt(II) complexes exhibited very high negative D values, while nickel(II) complexes showed very high positive D values. In the absence of an external magnetic field, the cobalt(II) complexes displayed barriers and slow relaxation of magnetization, highlighting the robustness of these complexes.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Rotaxane CoII Complexes as Field-Induced Single-Ion Magnets

Martina Cirulli et al.

Summary: Mechanically chelating ligands have potential for designing metal complexes, as demonstrated in Co-II-based single-ion magnets, with the ability to evaluate and understand magnetic properties through a combined experimental and theoretical approach.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Inorganic & Nuclear

Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

Andoni Zabala-Lekuona et al.

Summary: The discovery of Single-Molecule Magnets in 1993 revolutionized the field of information storage by shrinking the size of bits to molecular levels. Despite initially operating at temperatures near absolute zero, collaboration between chemists and physicists have led to the development of materials that can operate above liquid nitrogen temperatures. The evolution of SMMs has involved the study of various routes towards high performance materials, with each route essential for understanding the quantum dynamics behind these molecules.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

A Complete Ab Initio View of Orbach and Raman Spin-Lattice Relaxation in a Dysprosium Coordination Compound

Matteo Briganti et al.

Summary: This study highlights the unique electronic and magnetic properties of lanthanide molecular complexes, focusing on the importance of understanding spin-phonon relaxation mechanisms for further advancements in synthetic chemistry. By computing relaxation times ab initio and examining spin-phonon coupling mechanisms, the research provides a novel set of chemically sound design rules for addressing spin relaxation at any temperature, offering a comprehensive guide for the future development of the field.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Inorganic & Nuclear

Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks

M. Palacios-Corella et al.

Summary: The 1:2 and 1:1 Co(II) complexes of the L ligand have been synthesized and characterized for their structural and magnetic properties, showing octahedral high-spin Co(II) and field-induced slow relaxation of magnetization; one of the compounds has been incorporated into a bimetallic oxalate-based network leading to a novel 3D compound with ferromagnetic ordering, with EPR measurements suggesting weak magnetic coupling between the two sublattices.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Inorganic & Nuclear

A trapped hexaaqua CoII complex between the polyanionic sheets of decavanadate reveals high axial anisotropy and field induced SIM behaviour

Pradip Kumar Sahu et al.

Summary: In this work, a new inorganic compound [{Co(H2O)(6)}(2+){Na4V10O28}(2-)] (1) with unique magnetic properties is reported. Experimental observations and ab initio calculations reveal the specific magnetic behavior of the compound in relation to the decavanadate polyanions.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Inorganic & Nuclear

Alignment of axial anisotropy of a mononuclear hexa-coordinated Co(ii) complex in a lattice shows improved single molecule magnetic behavior over a 2D coordination polymer having a similar ligand field

Ajit Kumar Kharwar et al.

Summary: Two Co-II based complexes with distinct structures and magnetic properties were synthesized and characterized. Complex 1 exhibited a higher field-induced slow relaxation of magnetization at higher temperatures compared to complex 2. The alignment of anisotropic axes in complex 1 enhanced the axial anisotropy, resulting in a higher energy barrier.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Physical

Improvement of Ab Initio Ligand Field Theory by Means of Multistate Perturbation Theory

Lucas Lang et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

Incorporation of CrIII into a Keggin Polyoxometalate as a Chemical Strategy to Stabilize a Labile {CrIIIO4}Tetrahedral Conformation and Promote Unattended Single-Ion Magnet Properties

Nadiia I. Gumerova et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Inorganic & Nuclear

Trigonal Prismatic Cobalt(II) Single-Ion Magnets: Manipulating the Magnetic Relaxation Through Symmetry Control

Binling Yao et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Slow Magnetic Relaxation in a One-Dimensional Coordination Polymer Constructed from Hepta-Coordinate Cobalt(II) Nodes

Amit Kumar Mondal et al.

MAGNETOCHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Slow magnetic relaxation in penta-coordinate cobalt(II) field-induced single-ion magnets (SIMs) with easy-axis magnetic anisotropy

Salah S. Massoud et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Inorganic & Nuclear

Probing the Magnetic Anisotropy of Co(II) Complexes Featuring Redox-Active Ligands

Praveen Kumar et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Physical

Fine-Tuning of Uniaxial Anisotropy and Slow Relaxation of Magnetization in the Hexacoordinate Co(II) Complexes with Acidoligands

Yulia P. Tupolova et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

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Article Chemistry, Inorganic & Nuclear

Slow magnetization relaxation in a tetrahedrally coordinated mononuclear Co(II) complex exclusively ligated with phenanthroline ligands

Chen-Ming Wu et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Inorganic & Nuclear

Magnetic anisotropy in square pyramidal cobalt(II) complexes supported by a tetraazo macrocyclic ligand

Hui-Hui Cui et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Multidisciplinary

Single molecule magnet behaviour in a square planarS=1/2 Co(ii) complex and spin-state assignment of multiple relaxation modes

Indrani Bhowmick et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Inorganic & Nuclear

Structure, magnetic anisotropy and relaxation behavior of seven-coordinate Co(ii) single-ion magnets perturbed by counter-anions

Gangji Yi et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Inorganic & Nuclear

Slow magnetic relaxation in hexacoordinated cobalt(ii) field-induced single-ion magnets

Anna Switlicka et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

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Article Chemistry, Inorganic & Nuclear

Influence of ligand field on magnetic anisotropy in a family of pentacoordinate CoII complexes

Joydev Acharya et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Inorganic & Nuclear

A capped trigonal prismatic cobalt(II) complex as a structural archetype for single-ion magnets

Gangji Yi et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Multidisciplinary

Field-Induced Single-Ion Magnetic Behavior in Two Mononuclear Cobalt(II) Complexes

Yanfeng Cui et al.

CHEMISTRY-AN ASIAN JOURNAL (2019)

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Article Chemistry, Inorganic & Nuclear

Slow Magnetic Relaxation Triggered by a Structural Phase Transition in Long-Chain-Alkylated Cobalt(II) Single-Ion Magnets

Fumiya Kobayashi et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Magnetic Anisotropy in CoIIX4 (X=O, S, Se) Single-Ion Magnets: Role of Structural Distortions versus Heavy Atom Effect

Arup Sarkar et al.

CHEMISTRY-AN ASIAN JOURNAL (2019)

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Article Chemistry, Inorganic & Nuclear

Sizeable Effect of Lattice Solvent on Field Induced Slow Magnetic Relaxation in Seven Coordinated CoII Complexes

Arpan Mondal et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Inorganic & Nuclear

Zero-Field Slow Magnetic Relaxation and Hysteresis Loop in Four-Coordinate CoII Single-Ion Magnets with Strong Easy-Axis Anisotropy

Hui-Hui Cui et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Inorganic & Nuclear

Coligand Effects on the Field-Induced Double Slow Magnetic Relaxation in Six-Coordinate Cobalt(II) Single-Ion Magnets (SIMs) with Positive Magnetic Anisotropy

Julia Vallejo et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Inorganic & Nuclear

Field-Induced Slow Magnetic Relaxation in a Mononuclear Manganese(II) Complex

C. Rajnak et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

In-depth investigation of large axial magnetic anisotropy in monometallic 3d complexes using frequency domain magnetic resonance and ab initio methods: a study of trigonal bipyramidal Co(II)

Moya A. Hay et al.

CHEMICAL SCIENCE (2019)

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Article Chemistry, Inorganic & Nuclear

Field Induced Single Ion Magnetic Behaviour in Square-Pyramidal Cobalt(II) Complexes with Easy-Plane Magnetic Anisotropy

Amit Kumar Mondal et al.

MAGNETOCHEMISTRY (2019)

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Article Chemistry, Inorganic & Nuclear

Hydrogen-bonding interactions and magnetic relaxation dynamics in tetracoordinated cobalt(ii) single-ion magnets

Ryoji Mitsuhashi et al.

DALTON TRANSACTIONS (2019)

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Article Chemistry, Inorganic & Nuclear

Single-ion magnetic anisotropy in a vacant octahedral Co(II) complex

Amit Kumar Mondal et al.

DALTON TRANSACTIONS (2019)

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Article Chemistry, Inorganic & Nuclear

A Series of Field-Induced Single-Ion Magnets Based on the Seven-Coordinate Co(II) Complexes with the Pentadentate (N3O2) H2dapsc Ligand

Vyacheslav A. Kopotkov et al.

MAGNETOCHEMISTRY (2019)

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Review Chemistry, Multidisciplinary

Single Ion Magnets from 3d to 5f: Developments and Strategies

Min Feng et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

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Article Chemistry, Inorganic & Nuclear

Two polymorphic Co(II) field-induced single-ion magnets with enormous angular distortion from the ideal octahedron

I. Nemec et al.

DALTON TRANSACTIONS (2018)

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Article Chemistry, Inorganic & Nuclear

A new series of tetrahedral Co(ii) complexes [CoLX2] (X = NCS, Cl, Br, I) manifesting single-ion magnet features

Amit Kumar Mondal et al.

DALTON TRANSACTIONS (2018)

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Article Chemistry, Inorganic & Nuclear

Magnetic relaxation in cobalt( II)- based single- ion magnets influenced by distortion of the pseudotetrahedral [ N2O2] coordination environment

Michael Boehme et al.

DALTON TRANSACTIONS (2018)

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Article Chemistry, Inorganic & Nuclear

Slow magnetic relaxation influenced by change of symmetry from ideal Ci to D3d in cobalt(II)-based single-ion magnets

Lei Chen et al.

DALTON TRANSACTIONS (2018)

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Article Chemistry, Inorganic & Nuclear

Influence of the Coordination Environment on Easy-Plane Magnetic Anisotropy of Pentagonal Bipyramidal Cobalt(II) Complexes

Amit Kumar Mondal et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Inorganic & Nuclear

Important Role of Intermolecular Interaction in Cobalt(II) Single-Ion Magnet from Single Slow Relaxation to Double Slow Relaxation

Zhao-Bo Hu et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Inorganic & Nuclear

Slow Magnetic Relaxation in Cobalt(II) Field-Induced Single-Ion Magnets with Positive Large Anisotropy

Anna Switlicka et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Inorganic & Nuclear

Breaking the Magic Border of One Second for Slow Magnetic Relaxation of Cobalt-Based Single Ion Magnets

Roman Boca et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Inorganic & Nuclear

Construction and Magnetic Study of a Trigonal-Prismatic Cobalt(II) Single-Ion Magnet

Binling Yao et al.

INORGANIC CHEMISTRY (2018)

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Review Chemistry, Multidisciplinary

Coordination Clusters of 3d-Metals That Behave as Single-Molecule Magnets (SMMs): Synthetic Routes and Strategies

Diamantoula Maniaki et al.

FRONTIERS IN CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Two-Coordinate Co(II) Imido Complexes as Outstanding Single Molecule Magnets

Xiao-Nan Yao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Inorganic & Nuclear

Field-Supported Single-Molecule Magnets of Type [ Co(bzimpy) X2]

Cyril Rajnak et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Field-Induced Slow Magnetic Relaxation in Mononuclear Tetracoordinate Cobalt(II) Complexes Containing a Neocuproine Ligand

Lukas Smolko et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Field-Induced Co(II) Single-Ion Magnets with mer-Directing Ligands but Ambiguous Coordination Geometry

Yan Peng et al.

INORGANIC CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Probing the Effects of Ligand Field and Coordination Geometry on Magnetic Anisotropy of Pentacoordinate Cobalt(II) Single-Ion Magnets

Amit Kumar Mondal et al.

INORGANIC CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Field-Assisted Slow Magnetic Relaxation in a Six-Coordinate Co(II)-Co(III) Complex with Large Negative Anisotropy

Elena A. Buvaylo et al.

INORGANIC CHEMISTRY (2017)

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Determining Key Local Vibrations in the Relaxation of Molecular Spin Qubits and Single-Molecule Magnets

L. Escalera-Moreno et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2017)

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Article Chemistry, Inorganic & Nuclear

Syntheses, crystal structures and magnetic properties of two mixed-valence Co(III) Co(II) compounds derived from Schiff base ligands: field-supported single-ion-magnet behavior with easy-plane anisotropy

Shuvankar Mandal et al.

DALTON TRANSACTIONS (2017)

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Article Chemistry, Inorganic & Nuclear

A mononuclear Co(II) complex formed from pyridinedimethanol with manifold slow relaxation channels

Dusan Valigura et al.

DALTON TRANSACTIONS (2017)

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Article Chemistry, Multidisciplinary

Quantitative Estimation of Ising-Type Magnetic Anisotropy in a Family of C3-Symmetric CoII Complexes

Amit Kumar Mondal et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

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Article Chemistry, Multidisciplinary

Investigation of easy-plane magnetic anisotropy in P-ligand square-pyramidal CoII single ion magnets

Amit Kumar Mondal et al.

CHEMICAL COMMUNICATIONS (2017)

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Review Chemistry, Multidisciplinary

Understanding the Magnetic Anisotropy toward Single-Ion Magnets

Yin-Shan Meng et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

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Article Chemistry, Multidisciplinary

A carborane-incorporated mononuclear Co(II) complex showing zero-field slow magnetic relaxation

Deshuang Tu et al.

CHEMICAL COMMUNICATIONS (2016)

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Article Chemistry, Inorganic & Nuclear

Cobalt(II)-Based Single-Ion Magnets with Distorted Pseudotetrahedral [N2O2] Coordination: Experimental and Theoretical Investigations

Sven Ziegenbalg et al.

INORGANIC CHEMISTRY (2016)

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Article Chemistry, Inorganic & Nuclear

Probing the Effect of Axial Ligands on Easy-Plane Anisotropy of Pentagonal-Bipyramidal Cobalt(II) Single-Ion Magnets

Dong Shao et al.

INORGANIC CHEMISTRY (2016)

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Article Chemistry, Physical

Polymorphism in a Cobalt-Based Single-Ion Magnet Tuning Its Barrier to Magnetization Relaxation

Alexander A. Pavlov et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2016)

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Article Chemistry, Physical

Magnetic anisotropy of a CoII single ion magnet with distorted trigonal prismatic coordination: theory and experiment

Yan Peng et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

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Article Chemistry, Multidisciplinary

A low spin manganese(IV) nitride single molecule magnet

Mei Ding et al.

CHEMICAL SCIENCE (2016)

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The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

Jamie M. Frost et al.

CHEMICAL SCIENCE (2016)

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Article Multidisciplinary Sciences

A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier

Yvonne Rechkemmer et al.

NATURE COMMUNICATIONS (2016)

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Photo-activation of Single Molecule Magnet Behavior in a Manganese-based Complex

Ahmed Fetoh et al.

SCIENTIFIC REPORTS (2016)

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Article Chemistry, Multidisciplinary

Field-induced slow magnetic relaxation of octahedrally coordinated mononuclear Fe(III)-, Co(II)-, and Mn(III)-containing polyoxometalates

Rinta Sato et al.

CHEMICAL COMMUNICATIONS (2015)

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Tuning the Ising-type anisotropy in trigonal bipyramidal Co(II) complexes

Feng Shao et al.

CHEMICAL COMMUNICATIONS (2015)

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Article Chemistry, Multidisciplinary

Single-ion magnet behaviour of heptacoordinated Fe(II) complexes: on the importance of supramolecular organization

Arun Kumar Bar et al.

CHEMICAL COMMUNICATIONS (2015)

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Article Chemistry, Multidisciplinary

Uniaxial magnetic anisotropy of square-planar chromium(II) complexes revealed by magnetic and HF-EPR studies

Yi-Fei Deng et al.

CHEMICAL COMMUNICATIONS (2015)

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Review Chemistry, Multidisciplinary

3d single-ion magnets

Gavin A. Craig et al.

CHEMICAL SOCIETY REVIEWS (2015)

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Review Chemistry, Inorganic & Nuclear

Radical ligand-containing single-molecule magnets

Selvan Demir et al.

COORDINATION CHEMISTRY REVIEWS (2015)

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Review Chemistry, Inorganic & Nuclear

Large magnetic anisotropy in mononuclear metal complexes

Silvia Gomez-Coca et al.

COORDINATION CHEMISTRY REVIEWS (2015)

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Article Chemistry, Inorganic & Nuclear

Field-induced slow relaxation of magnetization in a pentacoordinate Co(II) compound [Co(phen)(DMSO)Cl2]

Ivan Nemec et al.

DALTON TRANSACTIONS (2015)

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Article Chemistry, Inorganic & Nuclear

A mononuclear Ni(II) complex: a field induced single-molecule magnet showing two slow relaxation processes

Jozef Miklovic et al.

DALTON TRANSACTIONS (2015)

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Observation of the single-ion magnet behavior of d(8) ions on two-coordinate Co(I)-NHC complexes

Yin-Shan Meng et al.

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Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni(II)

Katie E. R. Marriott et al.

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Field-Induced Slow Relaxation in a Monometallic Manganese(III) Single-Molecule Magnet

Gavin A. Craig et al.

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Ligands effects on the magnetic anisotropy of tetrahedral cobalt complexes

Mohamed R. Saber et al.

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Preparation and properties of a calcium(II)-based molecular chain decorated with manganese(II) butterfly-like complexes

A. C. Benniston et al.

DALTON TRANSACTIONS (2014)

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A Mononuclear Transition Metal Single-Molecule Magnet in a Nuclear Spin-Free Ligand Environment

Majed S. Fataftah et al.

INORGANIC CHEMISTRY (2014)

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Article Chemistry, Inorganic & Nuclear

Supramolecular Control over Molecular Magnetic Materials: γ-Cyclodextrin-Templated Grid of Cobalt(II) Single-Ion Magnets

Natalia Nedelko et al.

INORGANIC CHEMISTRY (2014)

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Electronic Structure and Slow Magnetic Relaxation of Low-Coordinate Cyclic Alkyl(amino) Carbene Stabilized Iron(I) Complexes

Prinson P. Samuel et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Article Chemistry, Multidisciplinary

Ising-type magnetic anisotropy and single molecule magnet behaviour in mononuclear trigonal bipyramidal Co(II) complexes

Renaud Ruamps et al.

CHEMICAL SCIENCE (2014)

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Origin of slow magnetic relaxation in Kramers ions with non-uniaxial anisotropy

Silvia Gomez-Coca et al.

NATURE COMMUNICATIONS (2014)

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Editorial Material Chemistry, Multidisciplinary

Geometry-Mediated Enhancement of Single-Ion Anisotropy: A Route to Single-Molecule Magnets with a High Blocking Temperature

Mamon Dey et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

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Article Chemistry, Multidisciplinary

Field-Induced Hysteresis and Quantum Tunneling of the Magnetization in a Mononuclear Manganese(III) Complex

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