期刊
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
卷 163, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2022.107222
关键词
Polymer-matrix composites (PMCs); Electrical properties; Interface; interphase; Foaming
资金
- Consortium for Cellular and Micro-Cellular Plastics (CCMCP)
- National Natural Science Foundation of China [51873132]
- Chinese Scholarship Council
The study showed that PDA@CNT/PVDF composites achieved desirable dielectric properties under supercritical CO2 foaming conditions, with significantly reduced dielectric permittivity and loss factor; increasing the expansion ratio helped reduce the polarizability within particle/polymer interfaces and promote the disaggregation of conductive particles; more nucleation points and space restrictions led to the formation of more cells, with mild growth in cell size, facilitating the reduction of inter-particle spacing and disentanglement.
Poly (vinylidene fluoride) (PVDF)-based microcellular dielectrics with polydopamine (PDA) coated carbon nanotubes (CNTs) were fabricated through scCO2 foaming technologies. Compared with pristine CNT/PVDF foam composites, the dielectric permittivity and loss factor of coated composites were much lower due to the significantly reduced polarizability within particle/polymer interfaces. Besides, these two parameters were also reduced with increasing expansion ratio, which was ascribed to the disaggregation of conductive particles and the increased air in the cells. Furthermore, it was demonstrated that more nucleation points initiated by the enlarged saturation pressure yielded the increased number of cells and the space restriction led to a mild growth of the cell size, which benefited for minimizing the increase of inter-particle spacing and the disentanglement between particles. Accordingly, the PDA@CNT/PVDF composites foamed to a high ER achieved a relatively large permittivity and an ultralow dielectric loss, which paved a new way to fabricate microcellular dielectrics.
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