期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 658, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.colsurfa.2022.130646
关键词
Photocatalysis; Peroxymonosulfate; Visible light; Degradation
The MIL-53Fe@g-C3N4 samples were prepared by solvothermal method and recorded as CM-x. The potocatalytic activity of the MIL-53Fe@g-C3N4 was significantly higher than MIL-53Fe, possibly due to the successful construction of a heterojunction promoting the migration and separation efficiency of photo-generated electron and hole pairs.
The MIL-53Fe@g-C3N4 samples were prepared by solvothermal method and recorded as CM-x. The potocatalytic activity of the MIL-53Fe@g-C3N4 was significantly higher than MIL-53Fe, and it might be due to the successfully constructed heterojunction promoting the migration and separation effciency of photo-generated electron and hole pairs. In order to further enhance the potocatalytic activity of the MIL-53Fe@g-C3N4, peroxymonosulfate was introduced into the MIL-53Fe@g-C3N4/Vis system, and the peroxymonosulfate could be simultaneously activated by photogenerated electron and iron to form sulfate radical under visible light irradiation. Therefore, the degradation efficiency of oxytetracycline hydrochloride was enhanced obviously. Meantime, the effects of peroxymonosulfate dosage, oxytetracycline hydrochloride concentration, temperature and pH on the degrada-tion efficiency of oxytetracycline hydrochloride were studied systematically. Meanwhile, the free radical catching experiments and electron spin resonance analysis confirmed that the main active substances were sulfate radical and hole. Finally, the mechanism and possible degradation pathways of MIL-53Fe@g-C3N4 acti-vating peroxymonosulfate to degrade oxytetracycline hydrochloride were proposed.
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