4.6 Article

Enhanced oil recovery performance of surfactant-enhanced Janus SiO2 nanofluid for high temperature and salinity reservoir

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DOI: 10.1016/j.colsurfa.2022.130545

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Janus SiO 2 nanoparticle; Dispersion stability; Adsorption; Anionic; non-ionic surfactant; Enhanced oil recovery

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This study investigates the dispersion stability of Janus SiO2 nanofluids and achieves good dispersion by introducing SDS/Tween 60 surfactant as a dispersant. Additionally, the variations of interfacial tension, emulsion stability, and wettability of the surfactant-enhanced Janus SiO2 nanofluid at different concentrations are studied. The experimental results demonstrate that the surfactant-enhanced Janus SiO2 nanofluid with a nanoparticle concentration of 0.01 wt% exhibits the best enhanced oil recovery performance.
To improve the dispersion stability of the nanofluid, SDS/Tween 60 surfactant solution was employed as the dispersant for the Janus SiO2 nanofluid. The compounded system showed good dispersion stability and oil displacement effect at high temperature (90 degrees C) and high salinity (35000 ppm). The amphiphilic Janus SiO2 nanoparticle was synthesized by Pickering emulsion method. Next, by introducing SDS/Tween60 surfactant system as a dispersant agent, the Janus SiO2 nanofluid could disperse well for more than 12 h at 90 degrees C with a salinity of 35000 ppm. The surfactant-enhanced Janus SiO2 nanofluids showed good dispersion stability in different characterization methods, including visual observation, Turbiscan stability index (TSI) and particle size. Based on the adsorption experiments, the optimal mass concentration ratio between surfactant and Janus nanoparticles was fixed at 2:1. The possible dispersion and stability mechanism of Janus SiO2 nanoparticles was explained from the perspective of the synergistic effect, between surfactants and nanoparticles and between surfactants and surfactants. Then, interfacial tension reduction ability, emulsion stability and wettability alter -nation capability of surfactant-enhanced Janus SiO2 nanofluid with various concentrations, were studied at 90 degrees C with a salinity of 35000 ppm. The surfactant-enhanced Janus SiO2 nanofluid, with a nanoparticle concentration of 0.01 wt%, showed the best EOR performance. The current study provides a new prospective in preparing Janus SiO2 nanofluids applied for enhanced oil recovery in high temperature and high salinity reservoirs.

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