ROS-responsive chlorin e6 and silk fibroin loaded ultrathin magnetic hydroxyapatite nanorods for T1-magnetic resonance imaging guided photodynamic therapy in vitro

Article Nanoscience & Nanotechnology

A Nanoarchitectonic Approach Enables Triple Modal Synergistic Therapies To Enhance Antitumor Effects

Zhimin Mo et al.

Summary: This study developed a nanoformulation GBD-Fe that integrated chemotherapy, chemodynamic therapy, and photothermal therapy, effectively enhancing the antitumor effects.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Chemistry, Multidisciplinary

Developing Efficient Small Molecule Acceptors with sp2-Hybridized Nitrogen at Different Positions by Density Functional Theory Calculations, Molecular Dynamics Simulations and Machine Learning

Asif Mahmood et al.

Summary: This study investigates the effect of nitrogen substitution on the performance of small molecule acceptors in organic solar cells. The results suggest that nitrogen substitution at the end-capping group is a better strategy for designing efficient small molecule acceptors.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

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Article Environmental Sciences

CuO nanoparticles decorated on hydroxyapatite/ferrite magnetic support: photocatalysis, cytotoxicity, and antimicrobial response

Elaine Cristina Paris et al.

Summary: In this study, photocatalytic CuO nanoparticles were successfully decorated on a magnetic support for efficient water remediation and bactericidal control under visible light irradiation. The nanocomposite exhibited high photocatalytic activity, magnetic recoverability, and low toxicity to the environment and organisms.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2022)

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Article Chemistry, Physical

Multifunctional phototheranostic nanoplatform based on polydopamine-manganese dioxide-IR780 iodide for effective magnetic resonance imaging-guided synergistic photodynamic/photothermal therapy

Zhimin Mo et al.

Summary: This work demonstrates the design and development of a multifunctional nanoplatform (PMIDA) for imaging-guided phototherapy, showing promising effects in facilitating intravenous injection of IR780 and achieving MRI-guided phototheranostic efficacy for tumor treatment.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Obstetrics & Gynecology

Clinical experience with an in-NICU magnetic resonance imaging system

Kirsten R. Thiim et al.

Summary: This study evaluated the utility of the 1T Embrace neonatal MRI scanner in a level III NICU. The results showed that the Embrace scans detected clinically relevant brain abnormalities and were comparable to the 3T scans in some cases.

JOURNAL OF PERINATOLOGY (2022)

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Article Chemistry, Multidisciplinary

Facile Synthesis of Multifunctional Magnetoplasmonic Au-MnO Hybrid Nanocomposites for Cancer Theranostics

Cong Tian et al.

Summary: This study focuses on the design of magnetoplasmonic nanohybrids for biomedical applications. The researchers successfully prepared plasmonic magnetic Au-MnO hybrid nanoparticles for imaging-guided photothermal therapy. The nanoparticles showed enhanced biocompatibility and absorption in the near-infrared region. Additionally, they exhibited promising contrast enhancement in T-1 MR imaging and produced sufficient heat for cancer cell ablation upon laser irradiation.

NANOMATERIALS (2022)

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Review Chemistry, Applied

From historical dye to bio-colourant: Processing, identification in historical textiles and potential applications of anthraquinone-based morindone

Khai Ly Do et al.

Summary: Recent interests of scientists in natural dyes have led to the development and application of ancient nature-based sources of colorants in textile production. This study focuses on anthraquinone-based morindone dye, exploring its biological sources, extraction, pigment modification, mordanting, dyeing methods, as well as recent works using analytical methods for practical utilization in historical textiles. The potential antimicrobial and ultraviolet protective performances of morindone dye are also analyzed for effective application in functional textiles.

DYES AND PIGMENTS (2022)

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Review Engineering, Biomedical

Manganese-based hollow nanoplatforms for MR imaging-guided cancer therapies

Shuang Liang et al.

Summary: This article introduces the theranostic nanoplatforms that integrate diagnostic and therapeutic functions, with a focus on hollow manganese (Mn)-based nanoplatforms. These platforms combine the advantages of hollow structures and theranostic features of Mn2+. The hollow cavity can encapsulate various small-molecule drugs for chemotherapy, photodynamic therapy, and photothermal therapy. After degradation in the tumor microenvironment, the released Mn2+ can serve as a magnetic resonance imaging contrast agent and a Fenton-like agent for chemodynamic therapy. Synergistic treatment outcomes can be achieved through reasonable design of the hollow nanosystems. Various Mn-based hollow nanoplatforms for MR imaging-guided cancer therapies are summarized, and potential obstacles and perspectives for translational applications are discussed.

BIOMATERIALS RESEARCH (2022)

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Review Chemistry, Physical

Oleic acid/oleylamine ligand pair: a versatile combination in the synthesis of colloidal nanoparticles

Stefanos Mourdikoudis et al.

Summary: In recent decades, various colloidal chemical approaches have been developed to synthesize nanostructured materials in controlled manner. This review focuses on the role of oleic acid/oleylamine ligand pair in the chemical synthesis of nanoparticles, discussing how the binding strengths and modes of these ligands affect the size and shape of the nanoparticles.

NANOSCALE HORIZONS (2022)

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Review Radiology, Nuclear Medicine & Medical Imaging

Alternatives to Gadolinium-Based Contrast Agents

Michael F. Tweedle

Summary: Gadolinium-based contrast agents have a exemplary safety record in the past 30 years, but recent challenges have sparked innovation efforts to find alternatives.

INVESTIGATIVE RADIOLOGY (2021)

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Article Nanoscience & Nanotechnology

Exploring the Unique Contrast Properties of Aptamer-Gadolinium Conjugates in Magnetic Resonance Imaging for Targeted Imaging of Thrombi

Anna Koudrina et al.

Summary: The study successfully prepared a fibrin-targeting MRI contrast agent, Gd(III)-NOTA-FA, which can specifically accumulate at the location of blood clots, enhancing contrast capabilities.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Materials Science, Ceramics

Effects of microwave processing parameters on the properties of nanohydroxyapatite: Structural, spectroscopic, hardness, and toxicity studies

Y. W. Sari et al.

Summary: This paper investigates the effects of microwave irradiation treatment on the properties of nanohydroxyapatite (nanoHAP) materials, highlighting the advantages of rapid heating, reduced reaction time, and increased productivity. Microwave irradiation is shown to facilitate the transformation of eggshell calcium into nanoHAP and the production of smaller particles with extended irradiation. Toxicity analysis reveals high cell viability of human embryonic cells after exposure to nanoHAP obtained from microwave irradiation treatment, indicating its potential as a biomaterial.

CERAMICS INTERNATIONAL (2021)

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Article Chemistry, Multidisciplinary

Solutions to the Drawbacks of Photothermal and Photodynamic Cancer Therapy

Xiangyu Deng et al.

Summary: Phototherapy, such as photothermal therapy and photodynamic therapy, has shown great potential in cancer treatment, but there are still many challenges that need to be addressed. Scientists are designing different systems to overcome the drawbacks associated with phototherapy, aiming to make it a more effective cancer treatment approach in clinical practice. This article discusses the problems and solutions in phototherapy research, providing insights for future advancements in the field.

ADVANCED SCIENCE (2021)

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Article Materials Science, Multidisciplinary

Magnetic hydroxyapatite nanocomposites: The advances from synthesis to biomedical applications

Asim Mushtaq et al.

Summary: Nanoscale magnetic hydroxyapatite nanoparticles have shown great potential in various biomedical applications, especially in cancer theranostics, due to their good stability and biocompatibility. Current research is focused on the controlled fabrication and structure-property relationships, while further exploration and development are needed in areas such as cancer treatment, tissue engineering, antimicrobial activity, etc. The multifunctional capabilities of MHAp nanoparticles and their potential in hybrid nanocarriers for biomedical applications are still being actively studied and improved.

MATERIALS & DESIGN (2021)

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Article Chemistry, Multidisciplinary

A Novel Mesoporous Superparamagnetic Hybrid Silica/Hydroxyapatite Nanocomposite as MRI Contrast Agent

Mehraneh Kermanian et al.

Summary: A novel magnetic hybrid silica/hydroxyapatite nanocomposite, MSFeHA, was successfully synthesized and studied as an MRI T2 contrast agent. The biocompatibility and bioaccumulation of the nanocomposite were evaluated through a series of experiments, showing potential clinical application value.

CHEMNANOMAT (2021)

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Article Materials Science, Multidisciplinary

Facile synthesis of Mn doped TiO2 rhombic nanocomposites for enhanced T1-Magnetic resonance imaging and photodynamic therapy

Asim Mushtaq et al.

Summary: A rhombic shaped manganese-doped titanium dioxide nanocomposite was designed to enhance the production of reactive oxygen species for photocatalysis and spin relaxation for MRI. Surface modification with Pluronic F-68 improved biocompatibility and physiological stability, while also showing promising efficacy in cancer cell imaging. The nanocomposite demonstrated significant positive contrast enhancement for MRI and synergistic photo-killing effects in vitro. These results suggest that the designed Mn-TiO2 nanocomposite is a promising multifunctional agent for both MRI and PDT applications.

MATERIALS RESEARCH BULLETIN (2021)

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Article Chemistry, Physical

Pluronic F-127/Silk Fibroin for Enhanced Mechanical Property and Sustained Release Drug for Tissue Engineering Biomaterial

Jina Youn et al.

Summary: An injectable thermosensitive hydrogel was developed for drug and cellular delivery, combining pluronic F-127 and silk fibroin. The addition of silk fibroin to pluronic F-127 improved mechanical strength, decreased degradation rate, and enhanced the release of hydrophobic drugs. The composite showed promising potential as a cell and drug delivery system for tissue engineering and regenerative medicine.

MATERIALS (2021)

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Article Chemistry, Physical

Hydroxyapatite with magnetic core: Synthesis methods, properties, adsorption and medical applications

Adrianna Biedrzycka et al.

Summary: This paper reviews the synthesis methods and properties of magnetic composites, including the combination of hydroxyapatite and iron oxide. These composites have a wide range of applications in environmental protection, medicine, and other fields.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2021)

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Article Polymer Science

Multifunctional 3D-Printed Magnetic Polycaprolactone/Hydroxyapatite Scaffolds for Bone Tissue Engineering

Mauro Petretta et al.

Summary: The study developed magnetically assisted PCL-HAp-1% SPION scaffolds, showing promising results in terms of cell proliferation and osteogenic potential, indicating the potential for further in vitro and in vivo studies and validations.

POLYMERS (2021)

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Article Materials Science, Biomaterials

Silk Fibroin/Collagen Blended Membrane Fabricated via a Green Papermaking Method for Potential Guided Bone Regeneration Application: In Vitro and In Vivo Evaluation

Dandan Luo et al.

Summary: The study utilized a green papermaking method to fabricate blended membranes of silk fibroin and collagen, which showed good biocompatibility and mechanical properties in wet conditions, appropriate biodegradation rate, improved osteoblast cell adhesion and proliferation, and induced a less severe inflammatory response, with a biodegradation time suitable for tissue regeneration, demonstrating promise for applications in guided bone regeneration.

ACS BIOMATERIALS SCIENCE & ENGINEERING (2021)

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Review Pharmacology & Pharmacy

Latest Innovations and Nanotechnologies with Curcumin as a Nature-Inspired Photosensitizer Applied in the Photodynamic Therapy of Cancer

Laura Marinela Ailioaie et al.

Summary: Photodynamic therapy is a minimally invasive treatment for eradicating cancer by using a photosensitizer to induce cell death in tumors. Current research focuses on integrating natural products into nanotechnologies to enhance targeting, reduce toxicity, and improve efficacy against various types of cancer.

PHARMACEUTICS (2021)

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Review Oncology

Nanomaterials for cancer therapy: current progress and perspectives

Zhe Cheng et al.

Summary: Nanomaterials play an important role in cancer therapy by targeting cancer cells, tumor microenvironment, and the immune system. However, despite an increasing number of studies, the approval of nano-drugs has not significantly increased, requiring further research to improve clinical translation efficiency.

JOURNAL OF HEMATOLOGY & ONCOLOGY (2021)

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Article Pharmacology & Pharmacy

siRNA-Loaded Hydroxyapatite Nanoparticles for KRAS Gene Silencing in Anti-Pancreatic Cancer Therapy

Dandan Luo et al.

Summary: A novel nanoparticle HAp-PEI/siKras was successfully fabricated for efficient targeted delivery of siRNA to pancreatic cancer cells, achieving successful gene silencing and tumor-targeted therapy. Experimental results confirmed its effectiveness in inhibiting pancreatic cancer cell proliferation in vitro, while exhibiting no cytotoxicity towards normal pancreatic cells.

PHARMACEUTICS (2021)

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Article Materials Science, Biomaterials

Development of copper vacancy defects in a silver-doped CuS nanoplatform for high-efficiency photothermal-chemodynamic synergistic antitumor therapy

Zizhen Qin et al.

Summary: The use of silver-doped copper sulfide nanoparticles (BSA-Ag:CuS) synthesized through a biomineralization strategy significantly enhanced the photothermal efficiency and near-infrared absorption capability of CuS nanoparticles, enabling 1064 nm laser-guided photothermal therapy. BSA-Ag:CuS nanoparticles demonstrated good stability, low toxicity, and strong antitumor ability in in vivo and in vitro biological experiments, showing promise as antitumor agents for future clinical cancer treatment.

JOURNAL OF MATERIALS CHEMISTRY B (2021)

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Article Materials Science, Biomaterials

Magnetic and radio-labeled bio-hybrid scaffolds to promote and track in vivo the progress of bone regeneration

Elisabetta Campodoni et al.

Summary: This study developed a bone tissue-mimetic scaffold functionalized with magnetic nanoparticles for in vivo monitoring of bone regeneration using MRI. The results showed that both naked and coated SPIONs were more uniformly distributed in the scaffold, demonstrating a suitable approach for developing biomaterials for long-term bone regeneration studies.

BIOMATERIALS SCIENCE (2021)

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Article Materials Science, Biomaterials

Facile synthesis of biocompatible magnetic titania nanorods for T1-magnetic resonance imaging and enhanced phototherapy of cancers

M. Zubair Iqbal et al.

Summary: Cancer treatment has been enhanced by nanomaterials with diagnostic and therapeutic effects, with a focus on MRI and phototherapy. Fe-TiO2 nanocomposites exhibit promising properties for cancer theranostics, showing potential for safe in vivo applications.

JOURNAL OF MATERIALS CHEMISTRY B (2021)

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Article Engineering, Environmental

Adsorption mercury, cobalt, and nickel with a reclaimable and magnetic composite of hydroxyapatite/Fe3O4/polydopamine

Rauf Foroutan et al.

Summary: The study enhanced the adsorptive performance of hydroxyapatite (HAp) using Fe3O4 magnetic nanoparticles and polydopamine (PDA), effectively removing Hg(II), Co(II), and Ni(II). The adsorption process was most efficient at pH 6, following Langmuir and Freundlich models, with a physical mechanism for removal. The composite material showed promising results in removing toxic metals from water sources.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Review Physics, Applied

Quantitative magnetic resonance imaging of brain anatomy and in vivo histology

Nikolaus Weiskopf et al.

Summary: Quantitative magnetic resonance imaging and in vivo histology aim to characterize tissue microstructure of living brain, providing deeper understanding of MRI tissue contrast and more accurate image parameters as compared to traditional histology methods.

NATURE REVIEWS PHYSICS (2021)

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Review Materials Science, Multidisciplinary

Emerging graphitic carbon nitride-based materials for biomedical applications

Guangfu Liao et al.

PROGRESS IN MATERIALS SCIENCE (2020)

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Article Medicine, Research & Experimental

Silk Fibroin-Modified Disulfiram/Zinc Oxide Nanocomposites for pH Triggered Release of Zn2+ and Synergistic Antitumor Efficacy

Ying-Zheng Zhao et al.

MOLECULAR PHARMACEUTICS (2020)

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Article Multidisciplinary Sciences

One-pot hydrothermal synthesis of a magnetic hydroxyapatite nanocomposite for MR imaging and pH-Sensitive drug delivery applications

Mehraneh Kermanian et al.

HELIYON (2020)

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Article Chemistry, Physical

Fe3O4@HAp core-shell nanoparticles as MRI contrast agent: Synthesis, characterization and theoretical and experimental study of shell impact on magnetic properties

Victoriya Zheltova et al.

APPLIED SURFACE SCIENCE (2020)

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Article Engineering, Environmental

A novel nanotheranostic agent for dual-mode imaging-guided cancer therapy based on europium complexes-grafted-oxidative dopamine

Yibiao Zou et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Materials Science, Biomaterials

Synthesis, characterization of copper oxide-gold nanoalloys and their peroxidase-like activity towards colorimetric detection of hydrogen peroxide and glucose

Sindisiwe Mvango et al.

MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS (2019)

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Article Nanoscience & Nanotechnology

Mechanically Strong Silica-Silk Fibroin Bioaerogel: A Hybrid Scaffold with Ordered Honeycomb Micromorphology and Multiscale Porosity for Bone Regeneration

Hajar Maleki et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Applied

Hydrothermal synthesis of hierarchical hollow hydroxyapatite microspheres with excellent fluoride adsorption property

Ming Gao et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2019)

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Article Materials Science, Ceramics

Optimized Zn-doped hydroxyapatite/doxorubicin bioceramics system for efficient drug delivery and tissue engineering application

Hyehyun Kim et al.

CERAMICS INTERNATIONAL (2018)

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Article Materials Science, Ceramics

Nano-hydroxyapatite bioactive glass composite scaffold with enhanced mechanical and biological performance for tissue engineering application

Sudip Mondal et al.

CERAMICS INTERNATIONAL (2018)

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Article Biotechnology & Applied Microbiology

The Wonders of Silk Fibroin Biomaterials in the Treatment of Breast Cancer

Pinar Tulay et al.

CRITICAL REVIEWS IN EUKARYOTIC GENE EXPRESSION (2018)

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Article Radiology, Nuclear Medicine & Medical Imaging

Low-Molecular-Weight Iron Chelates May Be an Alternative to Gadolinium-based Contrast Agents for T1-weighted Contrast-enhanced MR Imaging

Philipp Boehm-Sturm et al.

RADIOLOGY (2018)

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Article Pharmacology & Pharmacy

Real time monitoring and quantification of reactive oxygen species in breast cancer cell line MCF-7 by 2′,7′-dichlorofluorescin diacetate (DCFDA) assay

Daniela Figueroa et al.

JOURNAL OF PHARMACOLOGICAL AND TOXICOLOGICAL METHODS (2018)

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Article Clinical Neurology

Intraoperative Photodynamic Diagnosis Using Talaporfin Sodium Simultaneously Applied for Photodynamic Therapy against Malignant Glioma: A Prospective Clinical Study

Kazuhide Shimizu et al.

FRONTIERS IN NEUROLOGY (2018)

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Article Materials Science, Ceramics

Biomimetic synthesis of metal-hydroxyapatite (Au-HAp, Ag-HAp, Au-Ag-HAp): Structural analysis, spectroscopic characterization and biomedical application

Hyehyun Kim et al.

CERAMICS INTERNATIONAL (2018)

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Review Medicine, Research & Experimental

Iron Oxide Nanoparticle Based Contrast Agents for Magnetic Resonance Imaging

Zheyu Shen et al.

MOLECULAR PHARMACEUTICS (2017)

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Review Nanoscience & Nanotechnology

Magnetic hydroxyapatite: a promising multifunctional platform for nanomedicine application

Sudip Mondal et al.

INTERNATIONAL JOURNAL OF NANOMEDICINE (2017)

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Article Nanoscience & Nanotechnology

Energy Transfer in Ce0.85Tb0.15F3 Nanoparticles-CTAB Shell-Chlorin e6 System

Mykhaylo Yu. Losytskyy et al.

NANOSCALE RESEARCH LETTERS (2017)

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Article Oncology

Chlorin e6 conjugated silica nanoparticles for targeted and effective photodynamic therapy

Subramaniyan Bharathiraja et al.

PHOTODIAGNOSIS AND PHOTODYNAMIC THERAPY (2017)

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Article Materials Science, Coatings & Films

Nd:YAG (532 nm) pulsed laser deposition produces crystalline hydroxyapatite thin coatings at room temperature

G. C. Gomes et al.

SURFACE & COATINGS TECHNOLOGY (2017)

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Article Nanoscience & Nanotechnology

Energy Transfer in Ce0.85Tb0.15F3 Nanoparticles-CTAB Shell-Chlorin e6 System

Mykhaylo Yu. Losytskyy et al.

NANOSCALE RESEARCH LETTERS (2017)

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Article Chemistry, Multidisciplinary

Hydroxyapatite Coated Iron Oxide Nanoparticles: A Promising Nanomaterial for Magnetic Hyperthermia Cancer Treatment

Sudip Mondal et al.

NANOMATERIALS (2017)

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Article Nanoscience & Nanotechnology

MMP2-Targeting and Redox-Responsive PEGylated Chlorin e6 Nanoparticles for Cancer Near-Infrared Imaging and Photodynamic Therapy

Wenxiu Hou et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Article Chemistry, Physical

Uniform Fe3O4 microflowers hierarchical structures assembled with porous nanoplates as superior anode materials for lithium-ion batteries

Xiaoliang Wang et al.

APPLIED SURFACE SCIENCE (2016)

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Review Energy & Fuels

Triphenylamine based dyes for dye sensitized solar cells: A review

Asif Mahmood

SOLAR ENERGY (2016)

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Article Chemistry, Multidisciplinary

Synthesis of amine-polyglycidol functionalised Fe3O4@SiO2 nanocomposites for magnetic hyperthermia, pH-responsive drug delivery, and bioimaging applications

Madhappan Santha Moorthy et al.

RSC ADVANCES (2016)

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Article Materials Science, Coatings & Films

Nanoscale analysis of calcium phosphate films obtained by RF magnetron sputtering during the initial stages of deposition

Elvis O. Lopez et al.

SURFACE & COATINGS TECHNOLOGY (2015)

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Article Materials Science, Biomaterials

Silica-coated super-paramagnetic iron oxide nanoparticles (SPIONPs): a new type contrast agent of T-1 magnetic resonance imaging (MRI)

M. Zubair Iqbal et al.

JOURNAL OF MATERIALS CHEMISTRY B (2015)

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Article Chemistry, Physical

XPS analysis of oleylamine/oleic acid capped Fe3O4 nanoparticles as a function of temperature

D. Wilson et al.

APPLIED SURFACE SCIENCE (2014)

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Article Materials Science, Ceramics

Magnesium incorporated hydroxyapatite: Synthesis and structural properties characterization

Arghavan Farzadi et al.

CERAMICS INTERNATIONAL (2014)

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Article Chemistry, Multidisciplinary

Floxuridine-loaded silk fibroin nanospheres

Shuying Yu et al.

RSC ADVANCES (2014)

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Review Chemistry, Applied

Intermolecular interactions between natural polysaccharides and silk fibroin protein

Songmin Shang et al.

CARBOHYDRATE POLYMERS (2013)

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Article Biochemical Research Methods

Optimization in Solvent Selection for Chlorin e6 in Photodynamic Therapy

Shubhajit Paul et al.

JOURNAL OF FLUORESCENCE (2013)

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Review Chemistry, Physical

Recent Advances in Research Applications of Nanophase Hydroxyapatite

Kate Fox et al.

CHEMPHYSCHEM (2012)

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Article Chemistry, Inorganic & Nuclear

Hydrothermal Synthesis and Magnetic Properties of Fe3O4 Octahedral Microcrystals

Hua Jiao et al.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY (2012)

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Article Polymer Science

The influence of UV radiation on silk fibroin

A. Sionkowska et al.

POLYMER DEGRADATION AND STABILITY (2011)

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Article Biochemistry & Molecular Biology

Photosensitized oxidation of 2′,7′-dichlorofluorescin:: Singlet oxygen does not contribute to the formation of fluorescent oxidation product 2′,7′-dichlorofluorescein

P Bilski et al.

FREE RADICAL BIOLOGY AND MEDICINE (2002)

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ROS-responsive chlorin e6 and silk fibroin loaded ultrathin magnetic hydroxyapatite nanorods for T1-magnetic resonance imaging guided photodynamic therapy in vitro

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