Conceptual carbon-reduction process design and quantitative sustainable assessment for concentrating high purity ethylene from wasted refinery gas

The direct emission of waste refinery gas after combustion will cause a severe greenhouse effect. Recovering high-value-added ethylene from wasted refinery gas has fundamental economic and environ-mental significance. Due to the complexity of the composition of refinery waste gas, designing and opti-mizing the whole recovery process is still a challenging task. Herein, a novel process (SCOAS) was proposed to obtain polymer-grade ethylene from wasted refinery gas through a direct separation process, and heat pump-assisted thermal integration optimization (HPSCOAS) was carried out. The unique feature of the novel approach is that a new stripper and ethylene reabsorber follow the dry gas absorber to ensure ethylene recovery and methane content. An industrial model, shallow cooling oil absorption (SCOA), and concentration combined cold separation system of ethylene unit using wasted refinery gas was established to analyze the technology and environment. Based on the detailed process modeling and simulation results, the quantitative sustainability assessment of economy and environment based on product life cycle process is carried out. The results show that compared with the traditional process when the same product is obtained, the total annual cost of the HPSCOAS process is the lowest, which is 15.4% lower than that of the SCOA process and 6.1% lower than that of the SCOAS process. In addition, compared with the SCOA process and the HPSCOAS process, the SCOAS process has more environmental advantages. The non-renewable energy consumed by SCOAS is reduced by about 24.8% and 6.1%, respec-tively. The CO2 equivalent is reduced by about 38.6% and 23.7%.(c) 2022 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.

Automated summary

Obtaining polymer-grade ethylene from wasted refinery gas through a direct separation process has significant economic and environmental importance. The novel SCOAS process and heat pump-assisted thermal integration optimization (HPSCOAS) are proposed as efficient approaches. Compared to the traditional process, HPSCOAS has lower total annual cost and better environmental advantages.