4.7 Article

Metal contamination in sediments of dam reservoirs: A multi-facetted generic risk assessment

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CHEMOSPHERE
卷 310, 期 -, 页码 -

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2022.136760

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Sediment quality; Contamination indices; Ecotoxicity tests; Metal fractionation; Ecological and human health risk

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The quality of bottom sediments plays a crucial role in the functions of dam reservoirs. This study assesses the risk of metal contamination in sediments by combining different pollution indices. Zinc (Zn), lead (Pb), and cadmium (Cd) were found to dominate sediment contamination. Ecological risk assessment revealed high risks for all three metals, while human health risks were high for Pb and Cd. Sediments from the Rybnik reservoir posed a high potential ecological risk for Copper (Cu). The use of sequential BCR extraction and ecotoxicity analyses provided a comprehensive risk assessment of metal contamination in dam reservoir sediments.
The quality of bottom sediments is a key factor for many functions of dam reservoirs, which include water supply, flood control and recreation. The aim of the study was to combine different pollution indices in a critical generic risk assessment of metal contamination of bottom sediments. Both geochemical and ecological indices reflected that sediment contamination was dominated by Zn, Pb and Cd. The ecological risk indices suggested a high riks for all three metals, whereas human health risks were high for Pb and Cd. An occasional local contamination of sediments with Cr and Ni was revealed, although at levels not expected to cause concerns about potential ecological or health risk. Sediments from the Rybnik reservoir for Cu only revealed a high potential ecological risk. EF turned to be as being the most useful, whereas TRI ( n-ary sumation TRI) was the most important ecological index. All multi-element indices suggested similar trends, indicating that Zn, Pb and Cd taken altogether had the greatest impact on the level of sediment contamination and posed the greatest potential ecological and health risks to organisms. The use of sequential BCR extraction and ecotoxicity analyses allowed for a multi-facetted generic risk assessment of metals in sediments of dam reservoirs.

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