期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202203775
关键词
#alkyl-pi functional molecular liquids; distyrylbenzene; luminescence; substitution pattern modulation; viscosity
The development of alkyl-pi functional molecular liquids (FMLs) with desired liquid and optoelectronic properties is challenging. In this study, different alkyl chains were attached to different positions of alkyl-distyrylbenzene (DSB) to investigate their effects on the properties of liquid. It was found that the 2,5-C10C14 substituent pattern showed superior properties in terms of viscosity, optical properties, thermal stability, and photo-stability.
Alkyl-pi functional molecular liquids (FMLs) are of interest for fabricating soft electronic devices due to their fluidic nature and innate optoelectronic functions from the pi-conjugated moiety. However, predictable development of alkyl-pi FMLs with the desired liquid and optoelectronic properties is challenging. A series of alkyl-distyrylbenzene (DSB) liquids was studied in terms of the substituent position effect by attaching 2-octyldodecyl chains at (2,4-), (2,5-), (2,6-), and (3,5-). The effect of the alkyl chain length was investigated by attaching 2-hexyldecyl, 2-decyltetradecyl (C10C14), and 2-dodecylhexadecyl at the (2,5-) substituent position. The 2,5-C10C14 substituent pattern constructed a superior alkyl-DSB liquid with a lower viscosity, intrinsic optical properties, and high thermal- and photo-stabilities. The discovered 2,5-C10C14 was applied to dicyanostyrylbenzene and comparable liquid physical and optical superiorities were confirmed. This molecular design is useful for creating alkyl-pi FMLs with the aforementioned advantages, which are applicable for deformable and flowable optoelectronic devices.
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