期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 28, 期 64, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202203341
关键词
aggregation-induced emission; intermolecular interactions; nanoparticles; phosphorescence; platinum complexes
Five square-planar [Pt(C^N*N ')C'] complexes with novel nonsymmetric tetradentate ligands exhibit different photophysical properties and intermolecular interaction modes in solution and solid state, due to varying the structure of the metalating aromatic systems.
Five square-planar [Pt(C<^>N*N '<^>C ')] complexes (Pt1-Pt5) with novel nonsymmetric tetradentate ligands (L1-L5) were synthesized and characterized. Varying the structure of the metalating aromatic systems result in substantial changes in photophysical properties and intermolecular interaction mode of the complexes in solution and in solid state. The complexes are strongly emissive in tetrahydrofuran solution, with the band maxima ranging from 560 to 690 nm. Three of these complexes (Pt1, Pt2, Pt4) afford nanospecies upon injection of their solution into water, which show aggregation-induced emission (AIE) with a strong red shift of emission bands. In the solid state, crystalline samples of these complexes demonstrate mechanochromism upon grinding with a bathochromic shift of the emission. DFT and TD-DFT computational analysis of monomeric Pt1-Pt5 in solution and model dimeric emitters formed through intermolecular interaction of Pt1, Pt2, Pt4 molecules allowed assignment of observed AIE to the (MMLCT)-M-3 excited states of Pt-Pt bonded aggregates of these complexes.
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