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DMPO Spin Trapping Study of the Photolysis of 2-(4-Nitrophenyl)-1H-indolyl-3-methyl Derivatives

CHEMISTRY LETTERS (2023)

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2-(4-Nitrophenyl)-1H-indolyl-3-methyl Chromophore: A Versatile Photocage that Responds to Visible-light One-photon and Near-infrared-light Two-photon Excitations

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Summary: Due to UV light-induced cell damage, photoremovable protecting groups (PPGs) that can be removed using visible or near-infrared light have gained attention. A novel PPG, 2-(4-nitrophenyl)-1H-indolyl-3-methyl chromophore (NPIM), was synthesized. Various compounds were protected using this PPG and then deprotected using visible or near-infrared light. The low cytotoxicity of NPIM suggests its potential application in physiological studies.

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