He+ induced changes in the surface structure and optical properties of RF-sputtered amorphous alumina thin films

High quality 50 nm thick stoichiometric amorphous aluminium oxide films were reactively sputtered on microscope glass slide substrates. The films were exposed to energetic (2.20 MeV) He+ at different ion fluences of 6 x 10(12) ion/cm(2); 1 x 10(13) ion/cm(2); 2 x 10(13) ion/cm(2); 3 x 10(13) ion/cm(2); and 4 x 10(13) ion/cm(2). The effect of the ion irradiation on the optical, structural phase and surface properties of the alumina films was investigated via UV-VIS-NIR spectroscopy, X-ray diffraction analysis and the atomic force microscopy respectively. The transmission and absorption spectra of the irradiated films showed variation that depended on ion fluence. The refractive index, extinction coefficient optical conductivity, dielectric constant and energy loss functions of the films were also affected by He+ irradiation. Optical band gap and films' structural phase were however not altered by the ion irradiation. The variation in optical constants induced by radiation was attributed to electronic excitation and increase in surface roughness of the films. (C) 2015 Elsevier B.V. All rights reserved.