Achieving stable and fast potassium storage of Sb2S3@MXene anode via interfacial bonding and electrolyte chemistry

Article Chemistry, Multidisciplinary

Bi2S3 nanorods encapsulated in iodine-doped graphene frameworks with enhanced potassium storage properties

Yi Wei et al.

Summary: In this study, an iodine-doped graphene encapsulated Bi2S3 nanorods composite was proposed as an efficient anode material for potassium ion batteries, achieving high reversible capacity and good cycling stability.

CHINESE CHEMICAL LETTERS (2022)

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Article Chemistry, Multidisciplinary

Interfacial Covalent Bonding Endowing Ti3C2-Sb2S3 Composites High Sodium Storage Performance

Hui Wang et al.

Summary: This study successfully achieved Ti3C2-Sb2S3 composites by covalently bonding Sb2S3 uniformly on the surface of Ti3C2Tx MXene. The efficient interfacial chemical linkage bridged the physical gap and promoted the interfacial charge transfer efficiency, leading to a high reversible capacity and long cycling stability of the Ti3C2-Sb2S3 anode for sodium-ion batteries.

SMALL (2022)

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Article Chemistry, Multidisciplinary

Se-decorated SnO2/rGO composite spheres and their sodium storage performances

Peng Zhang et al.

Summary: The pomegranate-like SnO2/rGO/Se spheres exhibit superior sodium storage performances by alleviating the volume variation of SnO2 and facilitating rapid electron transfer, showing promising practical applicability in sodium-ion batteries.

CHINESE CHEMICAL LETTERS (2021)

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Article Nanoscience & Nanotechnology

Carbon Hollow Tube-Confined Sb/Sb2S3 Nanorod Fragments as Highly Stable Anodes for Potassium-Ion Batteries

Yuanji Wu et al.

Summary: Antimony-based materials are promising anode materials for potassium-ion batteries due to their high potassium storage capacity and low potassiation potential, but volume variation issues can lead to instability. Carbon coating and nanostructure design can alleviate this problem and improve the performance of the electrode.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Electrolyte-Mediated Stabilization of High-Capacity Micro-Sized Antimony Anodes for Potassium-Ion Batteries

Lin Zhou et al.

Summary: Alloying anodes have high capacity in potassium-ion batteries, but their capacity fading has limited practical applications. This study demonstrates that an antimony alloy anode can be stabilized by electrolyte engineering, delivering high and stable capacities without the need for nanostructural engineering or carbon modification. By tuning the K+ solvation structure through electrolyte composition, the study presents a new guideline for stabilizing metal-ion batteries using alloying anodes.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Achieving High-Performance 3D K+-Pre-intercalated Ti3C2Tx MXene for Potassium-Ion Hybrid Capacitors via Regulating Electrolyte Solvation Structure

Shuoqing Zhao et al.

Summary: A three-dimensional K+-pre-intercalated Ti3C2Tx MXene was constructed for efficient electrochemical potassium-ion storage, and the optimized solvation structure of the concentrated ether-based electrolyte led to the formation of a thin and inorganic-rich solid electrolyte interphase on the electrode, showing promising electrochemical performances. These results highlight the significant roles of rational structure design and electrolyte optimization for highly reactive MXene-based anode materials in energy storage devices.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Achieving High-Performance Metal Phosphide Anode for Potassium Ion Batteries via Concentrated Electrolyte Chemistry

Fuhua Yang et al.

Summary: Concentrated electrolyte is used to improve the cycling stability of potassium metal and potassium-ion batteries, mitigating the capacity degradation of metal phosphides and providing a feasible strategy for building high-energy-density potassium-ion batteries.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Three-Dimensional MOFs@MXene Aerogel Composite Derived MXene Threaded Hollow Carbon Confined CoS Nanoparticles toward Advanced Alkali-Ion Batteries

Long Yao et al.

Summary: This study presents a novel aerogel structure of MOFs@MXene to prevent aggregation of MXene nanosheets and enhance conductivity, as well as a (CoS NP@NHC)@MXene composite with excellent electrochemistry properties for use in lithium-ion, sodium-ion, and potassium-ion batteries. The hybrid system shows outstanding cycle stability, high capacities, and enhanced charge transfer kinetics, suggesting potential for practical electrochemical energy storage devices.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Stimulating the Reversibility of Sb2S3 Anode for High-Performance Potassium-Ion Batteries

Huiqiao Liu et al.

Summary: A strategy using Nb2O5 layers to confine sulfur species and facilitate reversible sulfide formation was proposed, leading to improved K-ion storage properties in Sb2S3 and SnS2 anodes. This approach demonstrated the highest K-ion diffusion coefficient, longest cycling stability, and excellent rate capability among controlled electrodes, showing potential for developing high-performance sulfides for KIBs.

SMALL (2021)

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Article Chemistry, Applied

Strongly coupled Te-SnS2/MXene superstructure with self-autoadjustable function for fast and stable potassium ion storage

Hongyang Sun et al.

Summary: An advanced superstructure anode Te-SnS2/MXene is designed to enhance the potassium-ion storage performance, featuring strong interface interaction and self-autoadjustable interlayer spacings.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Review Chemistry, Multidisciplinary

Water-in-Salt Electrolytes for Supercapacitors: A Review

Xue Tian et al.

Summary: Water-in-salt (WIS) electrolytes show great potential for application in supercapacitors due to their wide electrochemical stability window and other advantages, but also face challenges. This Review discusses the working mechanisms, reasons for the wide stability window, improvement strategies, and applications of WIS electrolytes in various types of supercapacitors.

CHEMSUSCHEM (2021)

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Article Chemistry, Physical

Interface-Engineered Fe3O4/MXene Heterostructures for Enhanced Lithium-Ion Storage

Peng Zhang et al.

Summary: Fe3O4/MXene hybrid heterostructures were successfully constructed using an interfacial self-assembly approach, resulting in an ideal arrangement where 70 wt% Fe3O4 exhibited enhanced capacity and stability during battery cycling. This dual-mode charge storage mechanism anticipates promising future applications for next-generation LIBs.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Multidisciplinary Sciences

Sb2S3-based conversion-alloying dual mechanism anode for potassium-ion batteries

Shaokun Chong et al.

Summary: The study demonstrates the construction of Sb2S3@rGO@NC as an anode for PIBs, achieving high initial charge capacity and long cycle life. In situ characterizations confirm the electrode undergoes a multi-electron transfer process and the dual mechanisms of K-ion insertion/extraction.

ISCIENCE (2021)

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Article Chemistry, Multidisciplinary

Flexible MXene Framework as a Fast Electron/Potassium-Ion Dual-Function Conductor Boosting Stable Potassium Storage in Graphite Electrodes

Bin Cao et al.

Summary: The use of Ti3C2Tx MXene nanosheets as a conductor in all-integrated graphite nanoflake/MXene electrodes greatly enhances potassium storage performance, exhibiting impressive cyclability and high energy/power densities. This design also provides new insights into phase transition mechanisms and demonstrates the potential for efficient potassium storage anodes.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Ten Years of Progress in the Synthesis and Development of MXenes

Michael Naguib et al.

Summary: Since their discovery in 2011, the number of 2D transition metal carbides and nitrides (MXenes) has steadily increased to over 40 compositions, potentially becoming the largest family of 2D materials. MXenes exhibit unique properties such as high electrical conductivity, which make them useful in various applications like energy storage and optoelectronics. The production of MXenes using methods like selective etching has led to rapid growth in research publications and patents, indicating promising commercialization potential.

ADVANCED MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Advances in the Synthesis of 2D MXenes

Yi Wei et al.

Summary: MXenes, versatile materials with adjustable structures and rich surface chemistry, have been recognized as potential 2D materials for various applications. Recent research has focused on synthetic routes, etching methods, and delamination strategies for large-scale preparation and stable storage. Antioxidation strategies for MXenes have also been summarized for future developments and practical applications.

ADVANCED MATERIALS (2021)

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Article Electrochemistry

Sb2S3 entrenched MWCNT composite as a low-cost Pt-free counter electrode for dye-sensitized solar cell and a viewpoint for a photo-powered energy system

I. John Peter et al.

Summary: By synthesizing Sb2S3 nanorods with MWCNT, a composite material suitable for Pt-free DSSCs and supercapacitors was successfully prepared, with the Sb2S3/CNT30 showing the best performance in battery testing. The composite material can improve the power conversion efficiency and exhibit good photovoltaic and capacitive performance.

ELECTROCHIMICA ACTA (2021)

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Editorial Material Materials Science, Ceramics

A decade of discovery: A review of MXenes, the family of 2D transition metal carbides and nitrides

Yury Gogotsi

AMERICAN CERAMIC SOCIETY BULLETIN (2021)

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Article Chemistry, Physical

Potassium-ion batteries using KFSI/DME electrolytes: Implications of cation solvation on the K+-graphite (co-)intercalation mechanism

Phuong Nam Le Pham et al.

Energy Storage Materials (2021)

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Article Nanoscience & Nanotechnology

MOF-Derived ZnS Nanodots/Ti3C2Tx MXene Hybrids Boosting Superior Lithium Storage Performance

Bin Cao et al.

Summary: The study successfully prepared ZnS nanodots/Ti3C2Tx MXene hybrids, which exhibit excellent cyclic stability and superior rate performance, providing new insights for enhancing lithium storage performance.

NANO-MICRO LETTERS (2021)

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Review Multidisciplinary Sciences

The world of two-dimensional carbides and nitrides (MXenes)

Armin Vahid Mohammadi et al.

Summary: MXenes, a family of two-dimensional materials, have diverse properties and wide-ranging applications in areas such as optics, catalysis, sensing, and medicine. Future research directions will focus on deepening the fundamental understanding of MXenes properties and exploring their potential for hybridization with other 2D materials.

SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Improved synthesis of Ti3C2Tx MXenes resulting in exceptional electrical conductivity, high synthesis yield, and enhanced capacitance

Ali Shayesteh Zeraati et al.

Summary: The EN-MILD synthesis approach has successfully produced high quality MXene sheets with exceptional electrical conductivity, high yield of delaminated single layers, and high colloidal concentrations, significantly expanding the applications of MXenes.

NANOSCALE (2021)

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Review Chemistry, Multidisciplinary

Advancements and Challenges in Potassium Ion Batteries: A Comprehensive Review

Ranjusha Rajagopalan et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Physical

K-Ion Storage Enhancement in Sb2O3/Reduced Graphene Oxide Using Ether-Based Electrolyte

Jinliang Li et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Boosting Potassium Storage Performance of the Cu2S Anode via Morphology Engineering and Electrolyte Chemistry

Qingkui Peng et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

In Situ Ice Template Approach to Fabricate 3D Flexible MXene Film-Based Electrode for High Performance Supercapacitors

Peng Zhang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Energy & Fuels

Influence of Surface Modifier Molecular Structures on the Photovoltaic Performance of Sb2S3-Sensitized TiO2 Nanorod Array Solar Cells

Chao Ying et al.

ENERGY TECHNOLOGY (2020)

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Article Chemistry, Physical

3D carbon-coated MXene architectures with high and ultrafast lithium/sodium-ion storage

Peng Zhang et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Encapsulating Ultrafine Sb Nanoparticles in Na+ Pre-Intercalated 3D Porous Ti3C2TX MXene Nanostructures for Enhanced Potassium Storage Performance

Ruizheng Zhao et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

In Situ Atomic-Scale Observation of Reversible Potassium Storage in Sb2S3@Carbon Nanowire Anodes

Yong Cheng et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Physical

Ionic-Conducting and Robust Multilayered Solid Electrolyte Interphases for Greatly Improved Rate and Cycling Capabilities of Sodium Ion Full Cells

Haocheng Yuan et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Nanoscience & Nanotechnology

A Sb2S3 Nanoflower/MXene Composite as an Anode for Potassium-Ion Batteries

Taohong Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Review Chemistry, Physical

Antimony-based nanomaterials for high-performance potassium-ion batteries

Hong Gao et al.

ECOMAT (2020)

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Article Chemistry, Physical

Encapsulating segment-like antimony nanorod in hollow carbon tube as long-lifespan, high-rate anodes for rechargeable K-ion batteries

Wen Luo et al.

NANO RESEARCH (2019)

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Review Multidisciplinary Sciences

Approaching high-performance potassium-ion batteries via advanced design strategies and engineering

Wenchao Zhang et al.

SCIENCE ADVANCES (2019)

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Article Chemistry, Multidisciplinary

Graphite Anode for a Potassium-Ion Battery with Unprecedented Performance

Ling Fan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Nanoscience & Nanotechnology

Plate-to-Layer Bi2MoO6/MXene-Heterostructured Anode for Lithium-Ion Batteries

Peng Zhang et al.

NANO-MICRO LETTERS (2019)

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Article Chemistry, Multidisciplinary

Amorphous Sb2S3 Nanospheres In-Situ Grown on Carbon Nanotubes: Anodes for NIBs and KIBs

Meng Li et al.

NANOMATERIALS (2019)

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Article Chemistry, Multidisciplinary

Electrolyte Chemistry Enables Simultaneous Stabilization of Potassium Metal and Alloying Anode for Potassium-Ion Batteries

Hua Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Electrochemistry

A highly Meso@Microporous carbon-supported Antimony sulfide nanoparticles coated by conductive polymer for high-performance lithium and sodium ion batteries

Weihao Yin et al.

ELECTROCHIMICA ACTA (2019)

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Hierarchically porous carbon supported Sn4P3 as a superior anode material for potassium-ion batteries

Deping Li et al.

ENERGY STORAGE MATERIALS (2019)

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An aqueous solution method towards Sb2S3 thin films for photoanodes

Panping Zhong et al.

CHEMICAL COMMUNICATIONS (2019)

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MoS2-on-MXene Heterostructures as Highly Reversible Anode Materials for Lithium-Ion Batteries

Chi Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Tunable pseudocapacitance storage of MXene by cation pillaring for high performance sodium-ion capacitors

Jianmin Luo et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Black Phosphorus Quantum Dot/Ti3C2 MXene Nanosheet Composites for Efficient Electrochemical Lithium/Sodium-Ion Storage

Ruijin Meng et al.

ADVANCED ENERGY MATERIALS (2018)

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Robust self-supported anode by integrating Sb2S3 nanoparticles with S,N-codoped graphene to enhance K-storage performance

Yanying Lu et al.

SCIENCE CHINA-CHEMISTRY (2017)

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Raman spectroscopic investigations of some Tl-sulfosalt minerals containing pyramidal (As,Sb)S3 groups

Sherif Kharbish

AMERICAN MINERALOGIST (2011)

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VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data

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Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy

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Achieving stable and fast potassium storage of Sb2S3@MXene anode via interfacial bonding and electrolyte chemistry

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