期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 4, 页码 442-445出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc05722k
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In this study, a novel catalyst was reported, which can selectively catalyze HMF-to-FDCA oxidation at ambient conditions with high efficiency, yield rate, and conversion. The catalyst also has the capability to simultaneously produce H2 and FDCA.
Here, we report that a Bi-doped Co3O4 nanosheet array grown on Ni foam can selectively catalyze HMF-to-FDCA oxidation at ambient conditions. The catalyst shows a faradaic efficiency of 97.7%, a yield rate of 362.5 mu mol h(-1), and a conversion of nearly 100%, surpassing those of pristine Co3O4. Furthermore, when the catalyst was adopted as both the anode and cathode in a two-electrode system, H-2 and FDCA can be produced simultaneously.
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