4.7 Article

Highly efficient copper-based halide single crystals with violet emission for visible light communication

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CHEMICAL COMMUNICATIONS
卷 59, 期 5, 页码 583-586

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc05965g

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K2CuBr3 single crystals synthesized by cooling-induced crystallization method exhibit violet emission and high photoluminescence quantum yield. They are also highly stable and capable of achieving a remarkable data transmission rate in visible light communication.
K2CuBr3 single crystals (SCs) are synthesized using a cooling-induced crystallization method with violet emission due to self-trapped excitons (STEs) under photoexcitation. The prepared K2CuBr3 SCs exhibit a high photoluminescence quantum yield (PLQY, 79.2%) and excellent stability against moisture, heat and UV light. When the K2CuBr3 SCs are used as a light source for visible light communication the data transmission rate reaches a striking 248 Mbps, which is more than 33-fold the -3 dB bandwidth.

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