4.7 Article

Circularly polarized luminescence and performance modulation of chiral europium-titanium (Eu2Ti4)-oxo clusters

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CHEMICAL COMMUNICATIONS
卷 59, 期 3, 页码 346-349

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc05816b

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Three pairs of chiral europium-titanium-oxo clusters with modest CPL characteristics and high QY levels (up to 79%) are reported, which can be regulated by switching between different ligand substituents.
The designed synthesis of chiral luminescent molecules with excellent circularly polarized luminescence (CPL) performance and high quantum yield (QY) levels has attracted great interest but remains very challenging. Herein, we report three pairs of chiral europium-titanium-oxo clusters featuring both modest CPL characteristics and high QY levels (up to 79%), which can be regulated by switching between different ligand substituents.

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