4.7 Article

Anionic ligand-induced chirality in perovskite nanoplatelets

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CHEMICAL COMMUNICATIONS
卷 59, 期 11, 页码 1485-1488

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc05469h

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Recently, perovskite materials modified by chiral ligands have demonstrated unique chiroptical activity and potential optoelectronic applications. However, the ligands have been limited to chiral amines. In this study, chiral phosphate molecules were utilized to synthesize CsPbBr3 nanoplatelets. The nanoplatelets exhibited distinct circular dichroism signal and retained their chiroptical properties after purification with anti-solvent.
Perovskite materials passivated by chiral ligands have recently shown unique chiroptical activity with promising optoelectronic applications. However, the ligands have been limited to chiral amines. Here, chiral phosphate molecules have been exploited to synthesize CsPbBr3 nanoplatelets. The nanoplatelets showed a distinct circular dichroism signal and maintained their chiroptical properties after purification with anti-solvent.

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