4.6 Article

Redox Behavior of In-O-Ti Interface for Selective Hydrogenation of CO2 to CO in Doped In-TiO2 Catalyst

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Multidisciplinary Sciences

Partially sintered copper-ceria as excellent catalyst for the high-temperature reverse water gas shift reaction

Hao-Xin Liu et al.

Summary: Constructing stable active sites in catalysts for high temperature catalytic reactions remains challenging. The authors successfully made stable copper clusters in the copper-ceria catalyst with high Cu loading (15 wt.%) for the high-temperature reverse water gas shift (RWGS) reaction, exhibiting unmatched activity and excellent durability.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Physical

CO2 Hydrogenation to Methanol over In2O3-Based Catalysts: From Mechanism to Catalyst Development

Jianyang Wang et al.

Summary: This review discusses recent advances in In2O3-based catalysts for CO2 hydrogenation, focusing on strategies to improve catalytic performance by facilitating active site formation, activating CO2 and H-2 for methanol synthesis, and stabilizing key intermediates. Mechanistic insights, including pathways of CO2 conversion and strategies for selective CO2 hydrogenation to methanol, are discussed, as well as future directions for development in this area.

ACS CATALYSIS (2021)

Article Chemistry, Physical

Reduction Behavior of Cubic In2O3 Nanoparticles by Combined Multiple In Situ Spectroscopy and DFT

Marc Ziemba et al.

Summary: In this study, the reduction behavior and oxygen dynamics of cubic In2O3 nanoparticles were elucidated using in situ Raman and UV-vis spectra combined with density functional theory (DFT) calculations. The results demonstrate the potential of combining different in situ spectroscopic methods with DFT to unravel the complex redox behavior of In2O3 nanoparticles. Oxygen exchange between the bulk and the surface of In2O3 nanoparticles was observed at elevated temperatures, leading to an oxidation of the surface and an increase in oxygen defects in the bulk.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Article Chemistry, Physical

Co Single Atoms in ZrO2 with Inherent Oxygen Vacancies for Selective Hydrogenation of CO2 to CO

Nazmul Hasan Md Dostagir et al.

Summary: The study presents a catalyst with isolated Co atoms in ZrO2 that enhances CO selectivity during CO2 hydrogenation by utilizing oxygen vacant sites. The synergy between Co and Zr is crucial for generating oxygen vacancies and stabilizing formate intermediates, leading to the control of product selectivity in CO2 hydrogenation reactions.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Unlocking the Catalytic Potential of TiO2-Supported Pt Single Atoms for the Reverse Water-Gas Shift Reaction by Altering Their Chemical Environment

Linxiao Chen et al.

Summary: This study shows a significant enhancement of activity on Pt/TiO2 SACs for the reverse water-gas shift reaction through a reduction-oxidation cycle, where reduction step increases accessibility of Pt-1 leading to higher activity. The research reveals how the structural evolution of Pt/TiO2 SACs impacts their catalytic efficiency.

JACS AU (2021)

Article Chemistry, Physical

Reverse water-gas shift reaction over Pt/MoOx/TiO2: reverse Mars-van Krevelen mechanism via redox of supported MoOx

Shinya Mine et al.

Summary: The study presents a MoOx/TiO2-supported Pt catalyst that efficiently promotes the reverse water-gas shift reaction at low temperature. The catalyst exhibits superior performance in CO2 conversion and selectivity compared to other catalysts. Operando X-ray absorption spectroscopy shows that the reaction follows the reverse Mars-van Krevelen mechanism.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Article Engineering, Environmental

Study on Cu-Fe/CeO2 bimetallic catalyst for reverse water gas shift reaction

Liang Chen et al.

Summary: In this study, a Cu-Fe bimetallic catalyst loaded on CeO2 was investigated for the RWGS reaction. The catalyst showed improved performance compared to an iron-free copper-based catalyst, achieving good selectivity and stability with a highest CO2 conversion rate of 42% at 750 degrees C. Exceeding 10% copper content in CeO2 led to decreased performance due to copper atom accumulation.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

Review Chemistry, Multidisciplinary

Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis

Xiao Jiang et al.

CHEMICAL REVIEWS (2020)

Article Multidisciplinary Sciences

U1 snRNP regulates cancer cell migration and invasion in vitro

Jung-Min Oh et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Methanol Synthesis at a Wide Range of H2/CO2Ratios over a Rh-In Bimetallic Catalyst

Molly Meng-Jung Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Physical

Supported mesoporous Cu/CeO2-δ catalyst for CO2 reverse water-gas shift reaction to syngas

Guilin Zhou et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

Article Chemistry, Multidisciplinary

Selective Methanol Carbonylation to Acetic Acid on Heterogeneous Atomically Dispersed ReO4/SiO2 Catalysts

Ji Qi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Physical

CuOx/CeO2 catalyst derived from metal organic framework for reverse water-gas shift reaction

Maria Ronda-Lloret et al.

APPLIED CATALYSIS A-GENERAL (2018)

Article Chemistry, Physical

Integrated tuneable synthesis of liquid fuels via Fischer-Tropsch technology

Jie Li et al.

NATURE CATALYSIS (2018)

Review Chemistry, Multidisciplinary

Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface

Shyam Kattel et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Multidisciplinary Sciences

A highly selective and stable ZnO-ZrO2 solid solution catalyst for CO2 hydrogenation to methanol

Jijie Wang et al.

SCIENCE ADVANCES (2017)

Article Chemistry, Multidisciplinary

CO2 Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity

Shyam Kattel et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation

Oliver Martin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Physical

The NixCe0.75Zr0.25-xO2 solid solution and the RWGS

Priscila C. Zonetti et al.

APPLIED CATALYSIS A-GENERAL (2014)

Article Materials Science, Multidisciplinary

Optical and transport properties of Ti-doped In2O3 thin films prepared by electron beam physical vapour deposition

J. Sanchez-Marcos et al.

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE (2010)

Article Chemistry, Physical

Enhanced Photoactivity of Oxygen-Deficient Anatase TiO2 Sheets with Dominant {001} Facets

Gang Liu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2009)

Article Chemistry, Multidisciplinary

Properties of Cu(thd)2 as a precursor to prepare Cu/SiO2 catalyst using the atomic layer epitaxy technique

Ching S. Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

Article Chemistry, Physical

Deactivation of supported copper metal catalysts for hydrogenation reactions

MV Twigg et al.

APPLIED CATALYSIS A-GENERAL (2001)