期刊
CERAMICS INTERNATIONAL
卷 49, 期 8, 页码 12012-12020出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.12.051
关键词
Oxygen vacancies; Energy transfer; Photoluminescence
In this study, Er3+ was doped in Bi3O4Br nano-crystal material to introduce impurity energy levels close to the intermediate band (IB) formed by oxygen vacancies defects. The density functional theory calculations confirmed the potential of tailored ground state carrier transition and enhancement of UC luminescence performance. The results showed a significant enhancement in UC emission intensity under excitation, paving the way for efficient UC nanosheet design through energy transfer (ET) combining matrix semiconductor with RE.
Lanthanide (Ln3+) ions doped upconversion (UC) nanosheets have attracted tremendous attention such as dis-plays, sensing, bioimaging and lasers etc, which was benefitting from the intriguing optical characters of Ln3+. However, the field of UC nanosheets has been hindered by low UC conversion efficiencies associate with non -radiative relation (NR) occurring by defect, the existence and influence of defects still cannot be eliminated completely. In this work, we design introduce the impurity energy level by doping Er3+in Bi3O4Br:Er3+ nano -crystal materials, which was closed with the intermediate band (IB) formed by oxygen vacancies defects. The density functional theory calculations confirm the IB energy level was closed with the intermediate excited states of Er3+, which provided the potential to tailored the ground state carriers transition from matrix semiconductor to Er3+ and thus tool to counteract the effect of NR and even enhance the UC luminescence performance. The photo-current results evidenced that the photocarrier success transition from IB to Er3+ intermediate excited states energy level leads to a sharp decrease in the surface carrier, on the contrary, the electron population on the excited state energy level of Er3+ have increased. As a result, compared with unmodified sample the UC emission intensity under excited by 980 nm of green and red is enhanced by 7 and 4 times respectively. This work paves the way to design efficient UC nanosheets through by energy transfer (ET) combine matrix semiconductor with RE and greatly enriches the understanding about the ET behavior of RE.
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