4.7 Article

Tuning ceramic content, mechanical and ablative properties of C/C-ZrC-ZrxCuy composites via using various C/C skeletons

期刊

CERAMICS INTERNATIONAL
卷 49, 期 8, 页码 12173-12185

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ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.12.069

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Ceramic matrix composites; Ablation property; High-temperature corrosion

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C/C-ZrC-ZrxCuy composites were prepared using pressure-assisted reactive melt infiltration with Zr2Cu alloy as an infiltrator. The mechanical and ablation properties of the composites were controlled by varying the C/C skeleton density. Higher ceramic content and lower skeleton density resulted in higher compressive and flexural strength. The composites with a skeleton density of 1.28 g/cm3 exhibited better mechanical and ablative properties at 2800 degrees C, with a linear ablation rate of 33.70 +/- 1.33 μm/s and a mass ablation rate of 22.39 +/- 2.99 mg/s after plasma flame ablation for 54 s.
C/C-ZrC-ZrxCuy composites were prepared by pressure-assisted reactive melt infiltration with Zr2Cu alloy as an infiltrator. The mechanical and ablation properties of C/C-ZrC-ZrxCuy composites were tuned by applying various C/C skeletons (1.28, 1.40, 1.58, and 1.73 g/cm3). When the C/C skeleton density increased from 1.28 to 1.73 g/cm3, the density of the composites decreased gradually. Additionally, due to the higher ceramic content, composites with low skeleton density (1.28, 1.40 g/cm3) exhibit a higher compressive and flexural strength. The fabricated composites with a skeleton density of 1.28 g/cm3 possess better mechanical properties and ablative properties at 2800 degrees C. After plasma flame ablation for 54 s, the linear and mass ablation rates of the composites are 33.70 +/- 1.33 mu m/s and 22.39 +/- 2.99 mg/s, respectively.

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