期刊
CERAMICS INTERNATIONAL
卷 49, 期 8, 页码 12885-12894出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.12.160
关键词
Hard; soft nanocomposites; Spinel ferrites; Magnetic properties; Electrodynamic properties
SrInxFe12-xO4/Ni0.5Zn0.5Fe2O4 (0.00 <= x <= 0.04) nanocomposites (SIFO/NZFO NCs) were synthesized using a one-pot sol-gel auto-combustion technique. The impact of indium doping on the magnetic properties of the nano-composites was investigated, and it was found that the saturation magnetization, remanence magnetization, and coercive field showed a non-monotonic dependence on the indium content.
SrInxFe12-xO4/Ni0.5Zn0.5Fe2O4 (0.00 <= x <= 0.04) nanocomposites (SIFO/NZFO NCs) were synthesized using a one-pot sol-gel auto-combustion technique. The EDX method was used to verify the chemical composition. An X-ray diffractometer (XRD) was used for the structural analysis. Scanning electron microscopy (SEM) was used to study the morphological characteristics. The impact of indium doping on the magnetic properties of the nano-composites was investigated using magnetization measurements at T = 300. A kink was observed in the M -H curves for lower indium content (x <= 0.02), which was suppressed with further increasing indium content until it vanished at a higher content. A single peak at a higher indium content replaced two peaks at a lower indium content (x 0.02), according to the switching field distribution (i.e., dM/dH vs. H). When the indium concentration increased, the saturation, remanence magnetization, and coercive field increased until x = 0.01, and then decreased, according to the analysis of the M -H loops. The obtained results reveal that an exchange interaction at the surface of the SIFO and NZFO nanoparticles (NPs) exists. The degree of intergranular dipolar interactions diminishes with increasing indium content within the hard-soft ferrite SIFO/NZFO NCs and becomes insignifi-cant at higher indium contents. Moreover, the core of the SIFO and NZFO NPs also contains magnetic super-exchange interactions between Fe and O ions. At high frequencies (2-20 GHz), a correlation was found be-tween the hard phase composition (indium content) and electrodynamic characteristics. Analyses were per -formed on the evolution of essential parameters (real and imaginary permittivity and permeability) in relation to the frequency. In this frequency range, the effect of electromagnetic radiation absorption was observed. A sig-nificant level of electromagnetic absorption (>-12 dB) in the frequency range was observed for investigated nanocomposites (NCs). The NCs with lower indium content (0.00 <= x <= 0.01) have higher reflection looses coefficients (-18 ...-36 dB). This opens broad perspectives for the practical application of magnetic media for intensive electromagnetic absorption.
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