期刊
CARBON
卷 201, 期 -, 页码 1001-1010出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2022.09.077
关键词
Carbon aerogel; Phase change materials; Electro-thermal conversion; Energy saving
Phase change materials (PCMs) have great potential for thermal storage and management, but their shape instability and poor thermal conductivity limit their applications. In this study, a three-dimensional carbon aerogel composite was prepared to support PCMs, enabling high thermal storage density and stable shape. The composites also showed effective solar/electro-thermal conversion. The work provides a feasible strategy for the preparation of multi-functional PCMs with broad application prospects.
Phase change materials (PCMs) have high energy storage density and stable phase transition temperature, and are one of the most promising thermal storage and management materials. However, the PCMs' shape instability, poor light absorption, low electrical and thermal conductivity seriously hinder their multi-functional application. Herein, a three-dimensional carbon aerogel with grid structure, large porosity, and hierarchical porous structure was prepared from resource-rich plant straw for supporting PCMs. Polyethylene glycol (PEG) as thermal energy guest was encapsulated into carbon aerogel by simple vacuum impregnation. The obtained PEG/carbon aerogel composites show high loading rate of PCMs(>97%), high thermal storage density (>185 J g-1), stable shape, and effective solar/electro-thermal conversion. The grid structure carbon aerogel as efficient thermal and elec-tron transfer pathways guarantee effective solar/electro-thermal conversion of composites. PEG encapsulated in each lattice as a thermal functional unit realizes the thermal storage and management. Especially, grid-structure composites realized fast and uniform electro-thermal conversion and storage under low voltage. This work provides a feasible, economic, and large-scale preparation strategy for the multi-functional PCMs. The multi-functional composites have broad application prospects in solar energy capture and storage, waste power recycling, building energy saving, smart thermal management and so on.
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