期刊
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
卷 -, 期 -, 页码 -出版社
WILEY
DOI: 10.1002/cjce.24829
关键词
kinetic modelling; method of moments; polyvinyl chloride; suspension polymerization; thermal runaway
A combined kinetic and heat transfer model is developed to study the kinetics and predict thermal runaway of vinyl chloride (VC) suspension polymerization. The model maps reactor temperature, monomer conversion, mole of initiator, radical concentrations, and average molecular properties during non-isothermal processes. Simulation results show that a lower jacket temperature and a larger heat transfer coefficient can delay or avoid the risk of thermal runaway. Model-based design is done to prevent thermal runaway by maintaining a 50°C isothermal process through fine-tuning the jacket temperature or heat transfer coefficient.
In the present study, a combined kinetic and heat transfer model was developed to study the kinetics and predict thermal runaway of vinyl chloride (VC) suspension polymerization. Reactor temperature, monomer conversion, mole of initiator, radical concentrations in the two phases (i.e., VC-rich phase and PVC-rich phase), and average molecular properties were mapped during non-isothermal processes. Meanwhile, the risk of thermal runaway was evaluated using S-Z (divergence) and H-J criteria. Simulation results show that a lower jacket temperature T-j and a larger heat transfer coefficient U are able to postpone or even avoid the risk of thermal runaway. Both of the criteria serve well for the prediction of thermal runaway during non-isothermal processes. To prevent the occurrence of thermal runaway to the greatest extent, model-based design of strategies for an isothermal polymerization process was done. Specifically, either jacket temperature T-j or heat transfer coefficient U can be fine-tuned to maintain a 50 & DEG;C isothermal process.
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