4.5 Review

A comprehensive review of properties of the biocompatible thin films on biodegradable Mg alloys

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Progress in bioactive surface coatings on biodegradable Mg alloys: A critical review towards clinical translation

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Summary: Mg and its alloys are promising candidates for biodegradable bone implants, cardiovascular stents, and wound closing devices. However, their rapid degradation rate hinders their clinical applications. Bio-functional surface coatings have emerged as a competent strategy to provide effective corrosion resistance and meet diverse clinical requirements.

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Summary: In this study, a corrosion-resistant Ni-Mo-P composite coating was deposited on the surface of AZ91D magnesium alloy substrate using electroless plating method, with varying concentrations of Ce(NO3)(3) and Nd(NO3)(3). The deposition mechanism of the Ni-Mo-P composite coating was explored, and the effects of Ce(NO3)(3) and Nd(NO3)(3) concentration on the microstructure and properties of the coating were studied. The results showed that the addition of optimal concentrations of Ce(NO3)(3) and Nd(NO3)(3) resulted in composite coatings with few defects, improved deposition rate, and enhanced adhesion to the magnesium alloy substrate. The corrosion rate of the Ni-Mo-P composite coatings was minimized at concentrations of 0.10 g/L for Ce(NO3)(3) and 1.00 g/L for Nd(NO3)(3), respectively. Additionally, compared to the addition of Ce(NO3)(3), the addition of Nd(NO3)(3) significantly improved the corrosion resistance of the Ni-Mo-P composite coating, as evidenced by a larger arc radius of capacitive resistance.

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Summary: This study presents an environmentally friendly strategy for enhancing the anti-corrosion properties of Mg alloy by coating it with chitosan-modified hydroxyapatite (HA) on the surface. The concentration of chitosan, immersion time, and pH of the post-treatment solution were investigated. The results showed that the HA-chitosan coating with chitosan concentration of 0.1 wt%, immersion time of 3 min, and pH of 8 exhibited the best anti-corrosion performance.

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Huaile Liu et al.

Summary: The present study aimed to improve stress corrosion cracking behavior of AZ31 magnesium alloy in Hanks' solution through laser shock peening (LSP) and subsequent phosphate conversion (PC). The results showed that the LSP/PC composite coating significantly enhanced the corrosion resistance and mechanical properties of the alloy, attributed to the formation of a dense coating by PC reaction and a strain strengthened layer induced by LSP pretreatment.

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Mingyu You et al.

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