Pure vs ultra-pure γ-alumina: A spectroscopic study and catalysis of ethanol conversion

Spectroscopic and catalytic properties of pure and ultrapure gamma-Al2O3 samples, both from Sasol, are compared. The pure sample has additional absorption in the UV region, much stronger luminescence in the Raman scattering experiments, slightly different skeletal surface OH groups IR spectra, and more evident features of weakly adsorbed pyridine. These effects are attributed to small amounts of Fe3+, Ti4+, surface silanol groups and Na+ ions. The ultrapure sample is more selective for the production of ethylene from ethanol at total conversion, while in the presence of oxygen is less active in oxidizing ethanol to other oxygenates and to COX. (C) 2015 Elsevier B.V. All rights reserved.