期刊
CATALYSIS COMMUNICATIONS
卷 67, 期 -, 页码 59-63出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2015.04.009
关键词
Biomass conversion; Cellulose; Isosorbide; Sugar alcohol; Heterogeneous catalysis
资金
- Japan Society for the Promotion of Science (JSPS) [25708028]
- Japan Association of Chemical Innovation (JACI) [H22-9]
- Grants-in-Aid for Scientific Research [25708028] Funding Source: KAKEN
One-pot conversion of cellulose to isosorbide was investigated by supported metal catalysts and ion-exchange resin in water. The maximum isosorbide yield using supported platinum catalysts and Amberlyst 70 was less than 30%. The isosorbide yield drastically increased with supported ruthenium catalysts instead of supported platinum catalysts and it also increased with the loading of ruthenium on carbon support. One-pot conversion of cellulose to isosorbide by 4 wt.% ruthenium catalyst and Amberlyst 70 proceeded with isosorbide yield of 55.8%. (C) 2015 Elsevier B.V. All rights reserved.
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