4.7 Article

High-performance flexible supercapacitors with hierarchical structured cathode (NiCo2O4/Au/MnO2) and anode (NiCo2S4/PPy)

期刊

APPLIED SURFACE SCIENCE
卷 605, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.apsusc.2022.154707

关键词

NiCo 2 O 4 nanoflowers; Flexible asymmetric supercapacitor; NiCo 2 O 4; Au; MnO 2 cathode; NiCo 2 S 4; PPy anode

资金

  1. R & D Projects in Key Fields of Guangdong Province [2020B0109380001, 2019B040403004, 2019B040403006]
  2. Natural Science Foundation of Guangdong, China [2021A1515012555]
  3. Natural Science Foundation of Guangzhou, China [202102080319]
  4. Fundamental Research Funds for the Central Universities [2020ZYGXZR012]

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In this study, NiCo2O4 nanoflowers with high specific surface area were prepared on nickel foam and used as cathode and anode for a flexible asymmetric supercapacitor. The hierarchical structured electrodes provided sufficient redox sites and channels for ion and electron transport. Furthermore, the performance of NiCo2S4/PPy as an anode was investigated for the first time, showing good cycling stability and specific capacitance.
NiCo2O4 nanoflowers with high specific surface area were prepared on nickel foam (NF) by hydrothermal method and used as frameworks for developing cathode and anode of flexible asymmetric supercapacitor. With the unique nanoflower-like NiCo2O4 arrays as skeleton, the NiCo2O4/Au/MnO2 cathode was prepared by goldspraying and electrochemical deposition and the NiCo2S4/PPy anode was prepared by second-hydrothermal and electro-polymerization. The hierarchical structured electrodes offer sufficient redox sites and adequate channels for accelerating ion and electron transport between electrodes and electrolyte. Moreover, the NiCo2S4/ PPy was first reported as the anode, and its cycling stability (capacitance retention of 86.04 % after 5000 cycles) and specific capacitance (1612.5F/g at 1 A/g). The assembled flexible all-solid-state asymmetric supercapacitor (NiCo2O4/Au/MnO2 // NiCo2S4/PPy) displays a high energy density of 206.37 Wh kg-1 at a power density of 398.57 W kg- 1 and an outstanding cyclability (capacitance retention of 83.41 % after 5000 cycles).

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