期刊
APPLIED PHYSICS LETTERS
卷 121, 期 24, 页码 -出版社
AIP Publishing
DOI: 10.1063/5.0131613
关键词
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资金
- National Natural Science Foundation of China (NSFC)
- Opened Fund of the State Key Laboratory on Integrated Optoelectronics
- [12174150]
- [62174066]
We demonstrate a method to faithfully excite an ultra-wide bandgap semiconductor hexagonal boron nitride (h-BN) using optical frequency upconversion technology. By using Yb3+ and Tm3+ as dual bridging sensitizers, we successfully excited NaYF4:Yb3+, Tm3+, and Gd3+ microcrystals with near-infrared light and generated high-energy excited states. A photoelectric conversion device was fabricated by attaching the microcrystals to the surfaces of the h-BN thin film. When irradiated with 980nm near-infrared light, the Gd3+ ions in the microcrystals populated high-energy excited states, emitting deep ultraviolet and vacuum ultraviolet fluorescence, providing enough energy for h-BN photoexcitation. Dynamic analysis reveals the important role of Forster resonance energy transfer in optical excitation, with populating Gd3+ ions to high-energy excited states being the key technical step.
We demonstrate a method to faithfully excite an ultra-wide bandgap semiconductor hexagonal boron nitride (h-BN) by using optical frequency upconversion technology. By means of Yb3+ and Tm3+ as dual bridging sensitizers, NaYF4:Yb3+, Tm3+, and Gd3+ microcrystals were excited by near-infrared light and generated high-energy (> 6 eV) excited states. We fabricated a photoelectric conversion device by attaching the microcrystals to the surfaces of the h-BN thin film. When the device was irradiated with 980-nm near-infrared light, the Gd3+ ions in the microcrystals were populated to the high-energy excited states (5)G(J) through an internal 7-photon process, emitting 205 nm deep ultraviolet fluorescence and 195.3 nm vacuum ultraviolet fluorescence, which provided enough energy for h-BN photoexcitation. Dynamic analysis showed that Forster resonance energy transfer played a very important role in the optical excitation, and populating Gd3+ ions to high-energy excited states was the technical key.
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