4.6 Article

Improved optical and magnetic properties of polycrystalline Z-type hexaferrites by co-precipitation method

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SPRINGER HEIDELBERG
DOI: 10.1007/s00339-022-06370-7

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Co-precipitation; Z-type hexaferrites; Ferrite; Ferrimagnetic; Magnetization; Antiferromagnetic

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Z-type hexaferrites with polycrystalline characteristics were synthesized using co-precipitation method. The XRD results confirmed the polycrystalline phase and 6 nm particle size of the Z-type ferrite nanoparticles. The FTIR spectrum showed resonances corresponding to tetrahedral and octahedral voids and a stabilized ferrite structure. These special ferrite materials exhibited ferrimagnetic properties and high coercivity, making them useful for microwave absorption, high-frequency applications, and magnetic recording media.
Z-type hexaferrites (HF) with polycrystalline characteristics were elegantly synthesized by co-precipitation. XRD results confirmed the Z-type ferrite nanoparticles as belonging to the polycrystalline phase and with a particle size of 6 nm. The FTIR spectrum exhibits low- and high-frequency resonances, which correspond to tetrahedral and octahedral voids and a stabilized ferrite structure. Optical properties were determined by visible light absorption between 200 and 500 nm in the UV-Vis broad reflectance spectrum. FE-SEM micrograph showed spongy morphology and strongly aggregated ions. VSM exhibits ferrimagnetic magnetic properties and got higher coercivity. These special ferrite materials will undoubtedly be useful in microwave absorption, high-frequency, and magnetic recording media.

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