Restriction of Re(VII) and Se(IV) diffusion by barite precipitation in compacted bentonite

The diffusion of anionic radionuclides in bentonite buffers for a high-level radioactive waste repository is only minimally retarded due to the anion exclusion effect and the low sorption onto the bentonite. In this study, barite precipitates in compacted barium-modified bentonite (Ba-bentonite) were used to study the restriction of the diffusion of Re(VII) and Se(IV). To this end, a synthetic porewater containing sulfate was placed in contact with compacted Ba-bentonite so that the sulfate ions could diffuse in the pores and produce barite precipitates. The Ba-bentonite and the bentonite with barium sulfate (BBS) retained the original interlayer structure based on X-ray diffractometer (XRD) analysis. Scanning electron microscopy (SEM) analysis revealed that the barite pre-cipitates were formed in the inter-aggregate pores. A through-diffusion method was employed to measure the effective diffusion coefficient and the rock capacity factor of Re(VII) and Se(IV) in compacted Gaomiaozi (GMZ) bentonite, Ba-bentonite, and BBS. The effective diffusion coefficient decreased with increasing the compacted dry density of the three bentonites, and it decreased with increasing the amount barite precipitates in the BBS. The diffusive flux was completely stopped by the formation of high amounts of barite precipitates. The relationship between the effective diffusion coefficient and the accessible porosity could be described by Archie's law. The cementation factor of BBS was 2.9 for Re(VII) and 3.2 for Se(IV). Compared to the GMZ and Ba-bentonites, the high cementation factor of the BBS indicated a low connectedness and/or a high tortuosity. It had a better clogging effect on anion diffusion than the Ba-and GMZ bentonites.

Automated summary

The diffusion of Re(VII) and Se(IV) in bentonite can be restricted by the formation of barite precipitates. The effective diffusion coefficient of these radionuclides decreases with the increase of barite precipitates. The formation of high amounts of barite precipitates can completely stop the diffusive flux.