期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 318, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2022.121874
关键词
Hydrothermal stability; Metal -oxide interaction; Steam reforming; Sintering; Rhodium
资金
- National Natural Science Foundation of China [21878169, 21991102]
- National Key R & D Program of China [2019YFA0905100]
Metal-sintering and carbon-deposition are two challenges in hydrogen production, but they can be effectively solved by using MgO-pre-coating support and MgO-post-coating confined metal-NPs strategy.
Metal-sintering and carbon-deposition are two bottlenecks in hydrocarbon (e.g., n-dodecane) steam reforming for hydrogen production. Effective inhibition of carbon-deposition by MgO-pre-coating support was intensively confirmed. Unfortunately, we found that weak interaction between Rh-NPs and MgO-pre-coating-CZO induced serious metal-sintering (4 -> 47 nm). To materialize bifunctional suppression, MgO-post-coating confined metal -NPs strategy is proposed. Under the conditions of 700 ?C, WHSV = 10 h(-1), and S/C = 3 for 50 h, negligible metal-sintering (4 -> 7 nm) and carbon-deposition (0.7 mg C/g cat.) occurred for 5%MgO-1%Rh-Ce0.75Zr0.25O2, whereas Rh-NPs grew to 36 nm and carbon-deposition was 25.6 mg C/g cat. for 1%Rh-Ce0.75Zr0.25O2. Owing to enhanced metal-support-interaction, formed MgO/Rh/CZO interfaces, and increased proportion of Rh-0, 5%MgO-1%Rh-Ce0.75Zr0.25O2 showed superior performance. DFT-based calculation results unveiled that MgO-post-coating increased the desorption energies of Rh cluster (0.21 -> 3.29 eV) and individual atoms (3.89 -> 4.35 eV). This study provides an efficient route for realizing sintering resistances of supported metal catalysts in high -temperature hydrothermal atmosphere.
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