Effects of WO3 doping on stability and N2O escape of MnOx-CeO2 mixed oxides as a low-temperature SCR catalyst

MnOx-WOx-CeO2 catalysts synthesized using a sol-gel method were investigated for the low-temperature NH3-SCR reaction. Among them, W0,1Mn0.4Ce0.5 mixed oxides exhibited above 80% NO conversion from 140 to 300 degrees C. In addition, this catalyst exhibited high stability and CO2 tolerance in a 50 h activity test at 150 degrees C. Substantially reduced N2O production and enhanced N-2 selectivity were achieved by WO3 doping, which was due to the weakened reducibility and increased number of add sites. The decreased SO2 oxidation activity as well as the reduced formation of ammonium and manganese sulfates resulted in a high SO2 resistance of this catalyst. (C) 2015 Elsevier B.V. All rights reserved.